N-annulated perylene fused porphyrins with enhanced near-IR absorption and emission
Type
ArticleKAUST Department
Biological and Environmental Sciences and Engineering (BESE) DivisionChemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2010-09-17Permanent link to this record
http://hdl.handle.net/10754/561523
Metadata
Show full item recordAbstract
N-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)3/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-β doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes. © 2010 American Chemical Society.Citation
Jiao, C., Huang, K.-W., Guan, Z., Xu, Q.-H., & Wu, J. (2010). N-Annulated Perylene Fused Porphyrins with Enhanced Near-IR Absorption and Emission. Organic Letters, 12(18), 4046–4049. doi:10.1021/ol1016383Sponsors
This work was financially supported by Singapore DSTA DIRP Project (DSTA-NUS-DIRP/2008/03), the NRF Competitive Research Program (R-143-000-360-281), and NUS Young Investigator Award (R-143-000-356-101) to J.W. and a KAUST baseline funding to K.-W.H.Publisher
American Chemical Society (ACS)Journal
Organic LettersPubMed ID
20734983ae974a485f413a2113503eed53cd6c53
10.1021/ol1016383
Scopus Count
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