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    A tristable [2]pseudo[2]rotaxane

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    Type
    Article
    Authors
    Trabolsi, Ali
    Fahrenbach, Albert C.
    Dey, Sanjeev Kumar
    Share, Andrew I.
    Friedman, Douglas C.
    Basu, Subhadeep
    Gasa, Travis B.
    Khashab, Niveen M. cc
    Saha, Sourav
    Aprahamian, Ivan
    Khatib, Hussam
    Flood, Amar H.
    Stoddart, Fraser Fraser Raser
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Biological and Environmental Sciences and Engineering (BESE) Division
    Chemical Science Program
    End User Computing
    Physical Science and Engineering (PSE) Division
    Smart Hybrid Materials (SHMs) lab
    Date
    2010
    Permanent link to this record
    http://hdl.handle.net/10754/561444
    
    Metadata
    Show full item record
    Abstract
    A strategy towards increasing the lifetime of the metastable state of a [2]rotaxane incorporating tetrathiafulvalene, 1,5-dioxynaphthalene and bipyridinium (BIPY 2+) is presented. Incorporation of BIPY 2+ served multiple roles as an electrostatic barrier to relaxation, a supramolecular recognition site for bis-1,5-dioxynaphthalene[38]crown-10 macrocycle, and upon reduction a recognition site for the mechanically bonded cyclobis(paraquat-p-phenylene) ring. © The Royal Society of Chemistry 2010.
    Citation
    Trabolsi, A., Fahrenbach, A. C., Dey, S. K., Share, A. I., Friedman, D. C., Basu, S., … Stoddart, J. F. (2010). A tristable [2]pseudo[2]rotaxane. Chemical Communications, 46(6), 871. doi:10.1039/b918321c
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/b918321c
    ae974a485f413a2113503eed53cd6c53
    10.1039/b918321c
    Scopus Count
    Collections
    Articles; Biological and Environmental Science and Engineering (BESE) Division; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Controlled Release and Delivery Laboratory; Chemical Science Program

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