Poly(3-hexylthiophene) - CdSe quantum dot bulk heterojunction solar cells: Influence of the functional end-group of the polymer
Murphy, John W.
Alshareef, Husam N.
Quevedo-López, Manuel Angel Quevedo
Biewer, Michael C.
Gnade, Bruce E.
Stefan, Mihaela C.
KAUST DepartmentFunctional Nanomaterials and Devices Research Group
Material Science and Engineering Program
Office of the VP
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/561416
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AbstractThe synthesis of H/thiol terminated P3HT from Br/allyl-terminated P3HT precursor was analyzed. The photovoltaic response of blends were prepared of H/thiol terminated P3HT with spherical CdSe quantum dots(QD) and compares the results with regioregular H/Br and Br/aryl-terminated P3HT. Phase segregation was carried by mixing relatively polar pyridine treated CdSe QD with nonpolar P3HT. The experiment revealed that a high loading of CdSe is necessary for an efficient charge transport and different loading ratios of CdSe has been investigated to correlate the photovoltaic response as a function of ration between donor H/thiol-P3ht polymer and acceptor Cdse QD. The results show that H/Br-P3HT, H/thiol- and Br/allyl-terminated P3HT exhibits better performance and Cdse quantum dots were used to obtain results.
CitationPalaniappan, K., Murphy, J. W., Khanam, N., Horvath, J., Alshareef, H., Quevedo-Lopez, M., … Stefan, M. C. (2009). Poly(3-hexylthiophene)−CdSe Quantum Dot Bulk Heterojunction Solar Cells: Influence of the Functional End-Group of the Polymer. Macromolecules, 42(12), 3845–3848. doi:10.1021/ma9006285
PublisherAmerican Chemical Society (ACS)