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    High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization

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    Type
    Article
    Authors
    Saidaminov, Makhsud I. cc
    Abdelhady, Ahmed L.
    Banavoth, Murali cc
    Alarousu, Erkki
    Burlakov, Victor M.
    Peng, Wei cc
    Dursun, Ibrahim cc
    Wang, Lingfei
    He, Yao
    Maculan, Giacomo
    Goriely, Alain cc
    Wu, Tao cc
    Mohammed, Omar F. cc
    Bakr, Osman cc
    KAUST Department
    Chemical Science Program
    Functional Nanomaterials Lab (FuNL)
    Imaging and Characterization Core Lab
    KAUST Catalysis Center (KCC)
    KAUST Solar Center (KSC)
    Laboratory of Nano Oxides for Sustainable Energy
    Material Science and Engineering Program
    Physical Science and Engineering (PSE) Division
    Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
    Date
    2015-07-06
    Online Publication Date
    2015-07-06
    Print Publication Date
    2015-12
    Permanent link to this record
    http://hdl.handle.net/10754/559595
    
    Metadata
    Show full item record
    Abstract
    Single crystals of methylammonium lead trihalide perovskites (MAPbX3; MA=CH3NH3+, X=Br− or I−) have shown remarkably low trap density and charge transport properties; however, growth of such high-quality semiconductors is a time-consuming process. Here we present a rapid crystal growth process to obtain MAPbX3 single crystals, an order of magnitude faster than previous reports. The process is based on our observation of the substantial decrease of MAPbX3 solubility, in certain solvents, at elevated temperatures. The crystals can be both size- and shape-controlled by manipulating the different crystallization parameters. Despite the rapidity of the method, the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPbX3 reported to date. The phenomenon of inverse or retrograde solubility and its correlated inverse temperature crystallization strategy present a major step forward for advancing the field on perovskite crystallization.
    Citation
    High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization 2015, 6:7586 Nature Communications
    Publisher
    Springer Nature
    Journal
    Nature Communications
    DOI
    10.1038/ncomms8586
    PubMed ID
    26145157
    Additional Links
    http://www.nature.com/doifinder/10.1038/ncomms8586
    Relations
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc24dw2j HANDLE: 10754/664283
    Is Supplemented By:
    • [Dataset]
      . DOI: 10.5517/ccdc.csd.cc24dw1h HANDLE: 10754/664289
    ae974a485f413a2113503eed53cd6c53
    10.1038/ncomms8586
    Scopus Count
    Collections
    Articles; Imaging and Characterization Core Lab; Physical Science and Engineering (PSE) Division; Chemical Science Program; Material Science and Engineering Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)

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