Electrical Properties of Ba3Ca1.18Nb1.82O9- Proton-Conducting Electrolyte Prepared by a Combustion Method
KAUST DepartmentMaterials Science and Engineering Program
Physical Sciences and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/555791
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AbstractBa3Ca1.18Nb1.82O9-δ (BCN18), regarded as a promising proton-conducting electrolyte material for solid oxide fuel cells, is usually synthesized by a solid-state reaction because of the limited choice of Nb precursors. This study presents a wet chemical route for preparing BCN18 powders that were then sintered into pellets. Electrochemical impedance spectroscopy studies indicated that BCN18 pellets show proton conductivity, since their total conductivity in wet air was significantly larger than that in dry air. However, a detailed analysis showed that only the BCN18 bulk behaves as a proton conductor, while its grain boundary conductivity did not increase in wet air.
CitationElectrical Properties of Ba3Ca1.18Nb1.82O9- Proton-Conducting Electrolyte Prepared by a Combustion Method 2013, 57 (1):1069 ECS Transactions
PublisherThe Electrochemical Society