To what extent can charge localization influence electron injection efficiency at graphene-porphyrin interfaces?
AuthorsParida, Manas R.
Aly, Shawkat Mohammede
Nagaraju, Doddahalli H.
Alshareef, Husam N.
Mohammed, Omar F.
KAUST DepartmentChemical Science Program
KAUST Solar Center (KSC)
Materials Science and Engineering Program
Physical Sciences and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/552281
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AbstractControlling the electron transfer process at donor- acceptor interfaces is a research direction that has not yet seen much progress. Here, with careful control of the charge localization on the porphyrin macrocycle using β -Cyclodextrin as an external cage, we are able to improve the electron injection efficiency from cationic porphyrin to graphene carboxylate by 120% . The detailed reaction mechanism is also discussed.
CitationTo what extent can charge localization influence electron injection efficiency at graphene-porphyrin interfaces? 2015 Phys. Chem. Chem. Phys.
PublisherRoyal Society of Chemistry (RSC)
JournalPhys. Chem. Chem. Phys.
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