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    A supermolecular building approach for the design and construction of metal–organic frameworks

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    c4cs00135d.pdf
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    Type
    Article
    Authors
    Guillerm, Vincent cc
    Kim, Dongwook cc
    Eubank, Jarrod F.
    Luebke, Ryan cc
    Liu, Xinfang
    Adil, Karim cc
    Lah, Myoung Soo
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2014-07-10
    Permanent link to this record
    http://hdl.handle.net/10754/550725
    
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    Abstract
    In this review, we describe two recently implemented conceptual approaches facilitating the design and deliberate construction of metal–organic frameworks (MOFs), namely supermolecular building block (SBB) and supermolecular building layer (SBL) approaches. Our main objective is to offer an appropriate means to assist/aid chemists and material designers alike to rationally construct desired functional MOF materials, made-to-order MOFs. We introduce the concept of net-coded building units (net-cBUs), where precise embedded geometrical information codes uniquely and matchlessly a selected net, as a compelling route for the rational design of MOFs. This concept is based on employing pre-selected 0-periodic metal–organic polyhedra or 2-periodic metal–organic layers, SBBs or SBLs respectively, as a pathway to access the requisite net-cBUs. In this review, inspired by our success with the original rht-MOF, we extrapolated our strategy to other known MOFs via their deconstruction into more elaborate building units (namely polyhedra or layers) to (i) elucidate the unique relationship between edge-transitive polyhedra or layers and minimal edge-transitive 3-periodic nets, and (ii) illustrate the potential of the SBB and SBL approaches as a rational pathway for the design and construction of 3-periodic MOFs. Using this design strategy, we have also identified several new hypothetical MOFs which are synthetically targetable.
    Citation
    A supermolecular building approach for the design and construction of metal–organic frameworks 2014, 43 (16):6141 Chem. Soc. Rev.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chem. Soc. Rev.
    DOI
    10.1039/C4CS00135D
    PubMed ID
    25009001
    Additional Links
    http://xlink.rsc.org/?DOI=C4CS00135D
    ae974a485f413a2113503eed53cd6c53
    10.1039/C4CS00135D
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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