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dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorLuebke, Ryan
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorWojtas, Lukasz
dc.contributor.authorWeseliński, Łukasz
dc.contributor.authorAl Kordi, Mohamed
dc.contributor.authorNorton, George
dc.contributor.authorCairns, Amy
dc.contributor.authorAdil, Karim
dc.date.accessioned2015-04-21T14:18:36Z
dc.date.available2015-04-21T14:18:36Z
dc.date.issued2015
dc.identifier.citationVersatile Rare Earth Hexanuclear Clusters for the Design and Synthesis of Highly-connected ftw-MOFs 2015 Chem. Sci.
dc.identifier.issn2041-6520
dc.identifier.issn2041-6539
dc.identifier.doi10.1039/C5SC00614G
dc.identifier.urihttp://hdl.handle.net/10754/550423
dc.description.abstractA series of highly porous MOFs were deliberately targeted to contain a 12-connected rare earth hexanuclear cluster and quadrangular tetracarboxylate ligands. The resultant MOFs have an underlying topology of ftw, (4, 12)-c ftw-MOFs. This targeted RE ftw-MOF platform offers potential to assess the effect of pore functionality and size, via ligand functionalization and/or expansion, on adsorption properties of relevant gases. Examination of gas adsorption properties of these compounds showed that the ftw-MOF-2 analogues, constructed from rigid ligands having a phenyl, a naphthyl or an anthracene core, exhibited a relatively high degree of porosity. The specific surface areas and pore volumes of these analogs are amongst the highest reported for rare earth based MOFs. Further studies reveal that Y-ftw-MOF-2 shows promising attributes as a storage media for methane (CH4) at high pressures. Furthermore, Y-ftw-MOF-2 shows potential as a separation agent for the selective removal of normal butane (n-C4H10) and propane (C3H8) from natural gas (NG) as well as interesting properties for the selective separation of n-C4H10 from C3H8 or isobutane (iso-C4H10).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/SC/C5SC00614G
dc.rightsThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.http://creativecommons.org/licenses/by/3.0/
dc.titleVersatile Rare Earth Hexanuclear Clusters for the Design and Synthesis of Highly-connected ftw-MOFs
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem. Sci.
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 Eas t Fowler Avenue, Tampa, Florida 33620, United States
kaust.personLuebke, Ryan
kaust.personBelmabkhout, Youssef
kaust.personWeselinski, Lukasz Jan
kaust.personCairns, Amy
kaust.personAdil, Karim
kaust.personEddaoudi, Mohamed
kaust.personAl Kordi, Mohamed
dc.relation.issupplementedbyDOI:10.5517/cc147nz0
dc.relation.issupplementedbyDOI:10.5517/cc147p02
dc.relation.issupplementedbyDOI:10.5517/cc147p13
refterms.dateFOA2018-06-14T04:56:59Z
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Luebke, R., Belmabkhout, Y., Weseliński, Ł. J., Cairns, A. J., Alkordi, M., Norton, G., … Eddaoudi, M. (2015). CCDC 1050062: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc147nz0. DOI: <a href="https://doi.org/10.5517/cc147nz0">10.5517/cc147nz0</a> HANDLE: <a href="http://hdl.handle.net/10754/624410">10754/624410</a></li><li><i>[Dataset]</i> <br/> Luebke, R., Belmabkhout, Y., Weseliński, Ł. J., Cairns, A. J., Alkordi, M., Norton, G., … Eddaoudi, M. (2015). CCDC 1050063: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc147p02. DOI: <a href="https://doi.org/10.5517/cc147p02">10.5517/cc147p02</a> HANDLE: <a href="http://hdl.handle.net/10754/624411">10754/624411</a></li><li><i>[Dataset]</i> <br/> Luebke, R., Belmabkhout, Y., Weseliński, Ł. J., Cairns, A. J., Alkordi, M., Norton, G., … Eddaoudi, M. (2015). CCDC 1050064: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc147p13. DOI: <a href="https://doi.org/10.5517/cc147p13">10.5517/cc147p13</a> HANDLE: <a href="http://hdl.handle.net/10754/624412">10754/624412</a></li></ul>


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