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C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorWang, Yuan
dc.contributor.authorZheng, Bin
dc.contributor.authorPan, Yupeng
dc.contributor.authorPan, Chengling
dc.contributor.authorHe, Lipeng
dc.date.accessioned2015-04-19T11:10:37Z
dc.date.available2015-04-19T11:10:37Z
dc.date.issued2015
dc.identifier.citationC-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex 2015 Dalton Trans.
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.pmid25893483
dc.identifier.doi10.1039/C5DT00787A
dc.identifier.urihttp://hdl.handle.net/10754/550320
dc.description.abstractA neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT00787A
dc.rightsDOI: 10.1039/C5DT00787A
dc.titleC-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalDalton Trans.
dc.eprint.versionPost-print
kaust.personHe, Lipeng
kaust.personHuang, Kuo-Wei
kaust.personWang, Yuan
kaust.personZheng, Bin
kaust.personPan, Yupeng
kaust.personPan, Chengling
dc.relation.issupplementedbyDOI:10.5517/cc148kzy
dc.relation.issupplementedbyDOI:10.5517/cc148l00
dc.relation.issupplementedbyDOI:10.5517/cc148l11
dc.relation.issupplementedbyDOI:10.5517/cc148l22
refterms.dateFOA2016-04-13T00:00:00Z
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050930: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148kzy. DOI: <a href="https://doi.org/10.5517/cc148kzy">10.5517/cc148kzy</a> HANDLE: <a href="http://hdl.handle.net/10754/624414">10754/624414</a></li><li><i>[Dataset]</i> <br/> Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050931: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l00. DOI: <a href="https://doi.org/10.5517/cc148l00">10.5517/cc148l00</a> HANDLE: <a href="http://hdl.handle.net/10754/624415">10754/624415</a></li><li><i>[Dataset]</i> <br/> Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l11. DOI: <a href="https://doi.org/10.5517/cc148l11">10.5517/cc148l11</a> HANDLE: <a href="http://hdl.handle.net/10754/624416">10754/624416</a></li><li><i>[Dataset]</i> <br/> Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l22. DOI: <a href="https://doi.org/10.5517/cc148l22">10.5517/cc148l22</a> HANDLE: <a href="http://hdl.handle.net/10754/624417">10754/624417</a></li></ul>


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