C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex
Abstract
A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.Citation
C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex 2015 Dalton Trans.Publisher
Royal Society of Chemistry (RSC)Journal
Dalton Trans.ISSN
1477-92261477-9234
PubMed ID
25893483Handle URI
http://hdl.handle.net/10754/550320Is Supplemented By
Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050930: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148kzyDOI:10.5517/cc148kzy
HANDLE:http://hdl.handle.net/10754/624414
Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050931: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l00
DOI:10.5517/cc148l00
HANDLE:http://hdl.handle.net/10754/624415
Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l11
DOI:10.5517/cc148l11
HANDLE:http://hdl.handle.net/10754/624416
Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l22
DOI:10.5517/cc148l22
HANDLE:http://hdl.handle.net/10754/624417