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    C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

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    C5DT00787A.pdf
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    Type
    Article
    Authors
    Huang, Kuo-Wei cc
    Wang, Yuan cc
    Zheng, Bin cc
    Pan, Yupeng
    Pan, Chengling
    He, Lipeng
    KAUST Department
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2015
    Permanent link to this record
    http://hdl.handle.net/10754/550320
    
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    Abstract
    A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.
    Citation
    C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex 2015 Dalton Trans.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Dalton Trans.
    DOI
    10.1039/C5DT00787A
    PubMed ID
    25893483
    Additional Links
    http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT00787A
    Relations
    Is Supplemented By:
    • [Dataset]
      Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050930: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148kzy. DOI: 10.5517/cc148kzy HANDLE: 10754/624414
    • [Dataset]
      Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050931: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l00. DOI: 10.5517/cc148l00 HANDLE: 10754/624415
    • [Dataset]
      Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l11. DOI: 10.5517/cc148l11 HANDLE: 10754/624416
    • [Dataset]
      Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l22. DOI: 10.5517/cc148l22 HANDLE: 10754/624417
    ae974a485f413a2113503eed53cd6c53
    10.1039/C5DT00787A
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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