Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures

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Type
Article
Authors
Zhang, Zhen
Zhang, Hefeng
Gnanou, Yves cc
Hadjichristidis, Nikos cc
KAUST Department
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Polymer Synthesis Laboratory
Date
2015
Permanent link to this record
http://hdl.handle.net/10754/550073

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Abstract
A novel strategy, based on the in situ generated Boron-thexyl-silaboracyclic initiating sites for the polyhomologation of dimethylsulfoxonium methylide, has been developed for the synthesis of complex polyethylene-based architectures. As examples, the synthesis of a 4-arm polyethylene star, three (polystyrene)(polyethylene)2 3-miktoarm stars and a PE-branched double graft copolymers are given.
Citation
Hadjichristidis, Nikos, Zhen Zhang, and Yves Gnanou. "Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures." Chemical Communications (2015).
Publisher
Royal Society of Chemistry (RSC)
Journal
Chem. Commun.
DOI
10.1039/C5CC01579K
PubMed ID
25900042
Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC01579K
Collections
Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.