Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures
Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Polymer Synthesis Laboratory
Date
2015Permanent link to this record
http://hdl.handle.net/10754/550073
Metadata
Show full item recordAbstract
A novel strategy, based on the in situ generated Boron-thexyl-silaboracyclic initiating sites for the polyhomologation of dimethylsulfoxonium methylide, has been developed for the synthesis of complex polyethylene-based architectures. As examples, the synthesis of a 4-arm polyethylene star, three (polystyrene)(polyethylene)2 3-miktoarm stars and a PE-branched double graft copolymers are given.Citation
Hadjichristidis, Nikos, Zhen Zhang, and Yves Gnanou. "Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures." Chemical Communications (2015).Publisher
Royal Society of Chemistry (RSC)Journal
Chem. Commun.PubMed ID
25900042Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC01579Kae974a485f413a2113503eed53cd6c53
10.1039/C5CC01579K
Scopus Count
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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