Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
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ArticleAuthors
Manzini, SimoneUrbina Blanco, César A.
Nelson, David J.
Poater, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M.Z.
Falivene, Laura
Cavallo, Luigi
Nolan, Steven P.
KAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2015-03Permanent link to this record
http://hdl.handle.net/10754/347339Metadata
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The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.Citation
Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene 2015, 780:43 Journal of Organometallic ChemistryPublisher
Elsevier BVAdditional Links
http://linkinghub.elsevier.com/retrieve/pii/S0022328X15000066Relations
Is Supplemented By:- [Dataset]
Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999049: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jldl. DOI: 10.5517/cc12jldl HANDLE: 10754/624315 - [Dataset]
Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999050: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jlfm. DOI: 10.5517/cc12jlfm HANDLE: 10754/624316