Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
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ArticleAuthors
Manzini, SimoneUrbina Blanco, César A.
Nelson, David J.
Poater, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M.Z.
Falivene, Laura
Cavallo, Luigi
Nolan, Steven P.
Date
2015-03Metadata
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The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.Citation
Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene 2015, 780:43 Journal of Organometallic ChemistryPublisher
Elsevier BVISSN
0022328XHandle URI
http://hdl.handle.net/10754/347339Is Supplemented By
Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999049: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jldlDOI:10.5517/cc12jldl
HANDLE:http://hdl.handle.net/10754/624315
Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999050: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jlfm
DOI:10.5517/cc12jlfm
HANDLE:http://hdl.handle.net/10754/624316