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dc.contributor.advisorEddaoudi, Mohamed
dc.contributor.authorLuebke, Ryan
dc.date.accessioned2014-11-30T10:59:31Z
dc.date.available2015-12-01T00:00:00Z
dc.date.issued2014-09
dc.identifier.citationLuebke, R. (2014). Metal-Organic Frameworks: Building Block Design Strategies for the Synthesis of MOFs. KAUST Research Repository. https://doi.org/10.25781/KAUST-H14L9
dc.identifier.doi10.25781/KAUST-H14L9
dc.identifier.urihttp://hdl.handle.net/10754/336368
dc.description.abstractA significant and ongoing challenge in materials chemistry and furthermore solid state chemistry is to design materials with the desired properties and characteristics. The field of Metal-Organic Frameworks (MOFs) offers several strategies to address this challenge and has proven fruitful at allowing some degree of control over the resultant materials synthesized. Several methodologies for synthesis of MOFs have been developed which rely on use of predetermined building blocks. The work presented herein is focused on the utilization of two of these design principles, namely the use of molecular building blocks (MBBs) and supermolecular building blocks (SBBs) to target MOF materials having desired connectivities (topologies). These design strategies also permit the introduction of specific chemical moieties, allowing for modification of the MOFs properties. This research is predominantly focused on two platforms (rht-MOFs and ftw-MOFs) which topologically speaking are edge transitive binodal nets; ftw being a (4,12)-connected net and rht being a (3,24)-connected net. These highly connected nets (at least one node having connectivity greater than eight) have been purposefully targeted to increase the predictability of structural outcome. A general trend in topology is that there is an inverse relationship between the connectivity of the node(s) and the number of topological outcomes. Therefore the key to this research (and to effective use of the SBB and MBB approaches) is identification of conditions which allow for reliable formation of the targeted MBBs and SBBs. In the case of the research presented herein: a 12-connected Group IV or Rare Earth based hexanuclear MBB and a 24-connected transition metal based SBB were successfully targeted and synthesized. These two synthetic platforms will be presented and used as examples of how these design methods have been (and can be further) utilized to modify existing materials or develop new materials for gas storage and separation applications for environmental and energy related applications including hydrogen, methane, carbon dioxide and hydrocarbon storage or separations.
dc.language.isoen
dc.subjectMOFs
dc.subjectSorption
dc.subjectDesign
dc.subjectMetal organic frameworks
dc.subjectPorous
dc.subjectCarbon dioxide
dc.titleMetal-Organic Frameworks: Building Block Design Strategies for the Synthesis of MOFs.
dc.typeDissertation
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.rights.embargodate2015-12-01
thesis.degree.grantorKing Abdullah University of Science and Technology
dc.contributor.committeememberPinnau, Ingo
dc.contributor.committeememberTakanabe, Kazuhiro
dc.contributor.committeememberZaworotko, Michael
thesis.degree.disciplineChemical Science
thesis.degree.nameDoctor of Philosophy
dc.rights.accessrightsAt the time of archiving, the student author of this dissertation opted to temporarily restrict access to it. The full text of this dissertation became available to the public after the expiration of the embargo on 2015-12-01.
refterms.dateFOA2015-12-01T00:00:00Z


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