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dc.contributor.authorLiu, J.
dc.contributor.authorShekhah, Osama
dc.contributor.authorStammer, X.
dc.contributor.authorArslan, H.K.
dc.contributor.authorLiu, B.
dc.contributor.authorSchupbach, B.
dc.contributor.authorTerfort, A.
dc.contributor.authorWoll, C.
dc.date.accessioned2014-11-11T14:33:06Z
dc.date.available2014-11-11T14:33:06Z
dc.date.issued2012-09-05
dc.identifier.citationLiu J, Shekhah O, Stammer X, Arslan HK, Liu B, et al. (2012) Deposition of Metal-Organic Frameworks by Liquid-Phase Epitaxy: The Influence of Substrate Functional Group Density on Film Orientation. Materials 5: 1581-1592. doi:10.3390/ma5091581.
dc.identifier.issn19961944
dc.identifier.doi10.3390/ma5091581
dc.identifier.urihttp://hdl.handle.net/10754/334637
dc.description.abstractThe liquid phase epitaxy (LPE) of the metal-organic framework (MOF) HKUST-1 has been studied for three different COOH-terminated templating organic surfaces prepared by the adsorption of self-assembled monolayers (SAMs) on gold substrates. Three different SAMs were used, mercaptohexadecanoic acid (MHDA), 4'-carboxyterphenyl-4-methanethiol (TPMTA) and 9-carboxy-10-(mercaptomethyl)triptycene (CMMT). The XRD data demonstrate that highly oriented HKUST-1 SURMOFs with an orientation along the (100) direction was obtained on MHDA-SAMs. In the case of the TPMTA-SAM, the quality of the deposited SURMOF films was found to be substantially inferior. Surprisingly, for the CMMT-SAMs, a different growth direction was obtained; XRD data reveal the deposition of highly oriented HKUST-1 SURMOFs grown along the (111) direction.
dc.language.isoen
dc.publisherMDPI AG
dc.rightsThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
dc.rightsArchived with thanks to Materials
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/
dc.subjectHKUST-1
dc.subjectMOF thin film
dc.subjectSAMs
dc.subjectFilm orientations
dc.subjectGold substrates
dc.subjectGrowth directions
dc.subjectMercaptohexadecanoic acid
dc.subjectMetal organic framework
dc.subjectOrganic surfaces
dc.subjectSams
dc.subjectTemplating
dc.subjectTriptycenes
dc.subjectXRD
dc.subjectAdsorption
dc.subjectEpitaxial growth
dc.subjectFunctional groups
dc.subjectJava programming language
dc.subjectSelf assembled monolayers
dc.subjectSubstrates
dc.titleDeposition of metal-organic frameworks by liquid-phase epitaxy: The influence of substrate functional group density on film orientation
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.identifier.journalMaterials
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionInstitute of Functional Interfaces, Karlsruhe Institute of Technology, Hermann-von-Helmholty-Platz 1, B 330, Eggenstein-Leopoldshafen D-76344, Germany
dc.contributor.institutionDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, United Kingdom
dc.contributor.institutionInstitute of Inorganic and Analytical Chemistry, Goethe-University Frankfurt am Main, Frankfurt 60438, Germany
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personShekhah, Osama
refterms.dateFOA2018-06-13T16:02:46Z


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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Except where otherwise noted, this item's license is described as This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.