Effects of aging temperature on electrical conductivity and hardness of Cu-3 at. pct Ti alloy aged in a hydrogen atmosphere
Name:
Article-Metallurgi-Effects_of-2011-08-01.pdf
Size:
938.2Kb
Format:
PDF
Description:
Article - Full Text
Type
ArticleKAUST Department
Physical Science and Engineering (PSE) DivisionDate
2011-02-25Online Publication Date
2011-02-25Print Publication Date
2011-08Permanent link to this record
http://hdl.handle.net/10754/334620
Metadata
Show full item recordAbstract
To improve the balance of the electrical conductivity and mechanical strength for dilute Cu-Ti alloys by aging in a hydrogen atmosphere, the influence of aging temperature ranging from 673 K to 773 K (400 °C to 500 °C) on the properties of Cu-3 at. pct Ti alloy was studied. The Vickers hardness increases steadily with aging time and starts to fall at 3 hours at 773 K (500 °C), 10 hours at 723 K (450 °C), or over 620 hours at 673 K (400 °C), which is the same as the case of conventional aging in vacuum. The maximum hardness increases from 220 to 236 with the decrease of aging temperature, which is slightly lower than aging at the same temperature in vacuum. The electrical conductivity at the maximum hardness also increases from 18 to 32 pct of pure copper with the decrease of the temperature, which is enhanced by a factor of 1.3 to 1.5 in comparison to aging in vacuum. Thus, aging at 673 K (400 °C) in a hydrogen atmosphere renders fairly good balance of strength and conductivity, although it takes nearly a month to achieve. The microstructural changes during aging were examined by transmission electron microscopy (TEM) and atom-probe tomography (APT), it was confirmed that precipitation of the Cu4Ti phase occurs first and then particles of TiH2 form as the third phase, thereby efficiently removing the Ti solutes in the matrix.Citation
Semboshi S, Nishida T, Numakura H, Al-Kassab T, Kirchheim R (2011) Effects of Aging Temperature on Electrical Conductivity and Hardness of Cu-3 at. pct Ti Alloy Aged in a Hydrogen Atmosphere. Metallurgical and Materials Transactions A 42: 2136-2143. doi:10.1007/s11661-011-0637-8.Publisher
Springer Natureae974a485f413a2113503eed53cd6c53
10.1007/s11661-011-0637-8
Scopus Count
The following license files are associated with this item:
Except where otherwise noted, this item's license is described as This is an Open Access article distributed under the terms of the Creative Commons-Attribution Noncommercial License, which permits unrestricted noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Related items
Showing items related by title, author, creator and subject.
-
Effect of alloying on elastic properties of ZrN based transition metal nitride alloysKanoun, Mohammed; Goumri-Said, Souraya (Surface and Coatings Technology, Elsevier BV, 2014-09) [Article]We report the effect of composition and metal sublattice substitutional element on the structural, elastic and electronic properties of ternary transition metal nitrides Zr1-xMxN with M=Al, Ti, Hf, V, Nb, W and Mo. The analysis of the elastic constants, bulk modulus, shear modulus, Young's modulus, and Poisson's ratio provides insights regarding the mechanical behavior of Zr1-xMxN. We predict that ternary alloys are more ductile compared to their parent binary compounds. The revealed trend in the mechanical behavior might help for experimentalists on the ability of tuning the mechanical properties during the alloying process by varying the concentration of the transition metal. © 2014 Elsevier B.V.
-
Large barocaloric effect with high pressure-driving efficiency in hexagonal MnNi0.77Fe0.23Ge alloyZeng, Qingqi; Shen, Jianlei; Liu, Enke; Xi, Xuekui; Wang, Wenhong; Wu, Guangheng; Zhang, Xixiang (arXiv, 2021-06-05) [Preprint]The hydrostatic pressure is expected to be an effective knob to tune the magnetostructural phase transitions of hexagonal MMX alloy. In this study, magnetization measurements under hydrostatic pressure were performed on a MMX martensitic MnNi0.77Fe0.23Ge alloy. The magnetostructural transition temperature can be efficiently tuned to lower temperatures by applying moderate pressures, with a giant shift rate of -151 K GPa-1. A temperature span of 30 K is obtained under the pressure, within which a large magnetic entropy change of -23 J kg-1 K-1 in a field change of 5 T is induced by the mechanical energy gain due to the large volume change. Meanwhile, a decoupling of structural and magnetic transitions is observed at low temperatures when the martensitic transition temperature is lower than the Curie temperature. These results show a multi-parameter tunable caloric effect that benefits the solid-state cooling.
-
Large barocaloric effect with high pressure-driving efficiency in hexagonal MnNi0.77Fe0.23Ge alloyZeng, Qingqi; Shen, Jianlei; Liu, Enke; Xi, Xuekui; Wang, Wenhong; Wu, Guangheng; Zhang, Xixiang (arXiv, 2021-06-05) [Preprint]The hydrostatic pressure is expected to be an effective knob to tune the magnetostructural phase transitions of hexagonal MMX alloy. In this study, magnetization measurements under hydrostatic pressure were performed on a MMX martensitic MnNi0.77Fe0.23Ge alloy. The magnetostructural transition temperature can be efficiently tuned to lower temperatures by applying moderate pressures, with a giant shift rate of -151 K GPa-1. A temperature span of 30 K is obtained under the pressure, within which a large magnetic entropy change of -23 J kg-1 K-1 in a field change of 5 T is induced by the mechanical energy gain due to the large volume change. Meanwhile, a decoupling of structural and magnetic transitions is observed at low temperatures when the martensitic transition temperature is lower than the Curie temperature. These results show a multi-parameter tunable caloric effect that benefits the solid-state cooling.