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dc.contributor.authorZhang, H. G.
dc.contributor.authorAlkayal, Nazeeha
dc.contributor.authorGnanou, Yves
dc.contributor.authorHadjichristidis, Nikos
dc.date.accessioned2014-11-11T14:28:05Z
dc.date.available2014-11-11T14:28:05Z
dc.date.issued2013-08-07
dc.identifier.citationZhang H, Alkayal N, Gnanou Y, Hadjichristidis N (2013) Anionic polymerization and polyhomologation: an ideal combination to synthesize polyethylene-based block copolymers. Chemical Communications 49: 8952. doi:10.1039/c3cc44928a.
dc.identifier.issn13597345
dc.identifier.pmid23963373
dc.identifier.pmid23963373
dc.identifier.doi10.1039/c3cc44928a
dc.identifier.urihttp://hdl.handle.net/10754/334518
dc.description.abstractA novel one-pot methodology combining anionic polymerization and polyhomologation, through a "bridge" molecule (BF3OEt 2), was developed for the synthesis of polyethylene (PE)-based block copolymers. The anionically synthesized macroanion reacts with the "bridge" molecule to afford a 3-arm star (trimacromolecular borane) which serves as an initiator for the polyhomologation. 2013 The Royal Society of Chemistry.
dc.language.isoen
dc.publisherRoyal Society of Chemistry (RSC)
dc.rightsThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
dc.rightsArchived with thanks to Chemical Communications
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/
dc.subjectcopolymer
dc.subjectpolyethylene derivative
dc.subjectchemical reaction
dc.subjectmethodology
dc.subjectmolecule
dc.subjectpolyhomologation
dc.subjectpolymerization
dc.subjectsynthesis
dc.subjectAnions
dc.subjectButadienes
dc.subjectElastomers
dc.subjectPolyethylene
dc.subjectPolymerization
dc.subjectPolymers
dc.subjectPolystyrenes
dc.titleAnionic polymerization and polyhomologation: An ideal combination to synthesize polyethylene-based block copolymers
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentPolymer Synthesis Laboratory
dc.identifier.journalChemical Communications
dc.eprint.versionPublisher's Version/PDF
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personZhang, Hefeng
kaust.personGnanou, Yves
kaust.personHadjichristidis, Nikos
kaust.personAlkayal, Nazeeha
refterms.dateFOA2018-06-13T15:40:54Z
dc.date.published-online2013-08-07
dc.date.published-print2013


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This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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