KAUST DepartmentComputational Physics and Materials Science (CPMS)
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Online Publication Date2013-08-13
Print Publication Date2013-08-14
Permanent link to this recordhttp://hdl.handle.net/10754/315780
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AbstractUsing electronic structure calculations, we systematically investigate the formation of vacancies in III-V semiconductors (III = Al, Ga, and In and V = P, As, and Sb), for a range of charges ( −3≤q≤3 ) as a function of the Fermi level and under different growth conditions. The formation energies were corrected using the scheme due to Freysoldt et al. [Phys. Rev. Lett. 102, 016402 (2009)] to account for finite size effects. Vacancy formation energies were found to decrease as the size of the group V atom increased. This trend was maintained for Al-V, Ga-V, and In-V compounds. The negative-U effect was only observed for the arsenic vacancy in GaAs, which makes a charge state transition from +1 to –1. It is also found that even under group III rich conditions, group III vacancies dominate in AlSb and GaSb. For InSb, group V vacancies are favoured even under group V rich conditions.
CitationTahini HA, Chroneos A, Murphy ST, Schwingenschlögl U, Grimes RW (2013) Vacancies and defect levels in III-V semiconductors. Journal of Applied Physics 114: 063517. doi:10.1063/1.4818484.
JournalJournal of Applied Physics