Ferroelectric materials have emerged as promising candidates for piezoelectric nanogenerators, attributed to their superior energy conversion efficiency derived from inherent polarization characteristics. Polar metal–ligand assemblies represent advantageous alternatives to conventional inorganic ceramics and organic polymers, offering tunable electronic properties, environmental benignity, and enhanced energy conversion capabilities. We demonstrate an octahedral [Co6(H2O)12(TPTA)812·50H2O] cage assembly exhibiting pronounced ferroelectric behavior, characterized by a P–E hysteresis loop with a remnant polarization of 6.84 μC cm–2. The ferroelectric and piezoelectric properties of 1 were unambiguously confirmed through the visualization of electrical domains in single crystals and crystalline thin films via piezoresponse force microscopy (PFM). Single-point, bias-dependent PFM spectroscopy measurements revealed characteristic amplitude-butterfly and phase-hysteresis loops, substantiating the piezoelectric nature of the material. Piezoelectric energy harvesting investigations conducted on polydimethylsiloxane (PDMS) composite materials revealed a maximum peak output voltage of 12.20 V and a power density of 14.85 μW cm–2 for the optimized 20 wt % 1-PDMS composite device. The practical utility was validated through the implementation of a smart pressure sensor, wherein a mat device, constructed from five parallel-connected independent devices, successfully functioned as a sensor capable of illuminating a commercial LED under gentle mechanical stimulation. These findings establish the potential of this cage system for integration into self-powered sensor technologies.

Inverted perovskite solar cells face performance limitations due to non-radiative recombination at the perovskite surfaces in devices, including functional layers. Advanced characterization and density functional theory reveal that phosphonic acids passivate perovskite surface defects, while piperazinium chloride mitigates interface recombination by improving energy level alignment, introducing a field effect, and homogenizing the surface. Together, the quasi-Fermi level splitting of the perovskite is homogeneously increased by ca. 100mV. This enables two-terminal perovskite-on-silicon tandems to achieve a certified open-circuit voltage of 2V for a 1 cm² device and high performance in excess of 31%. The scalability of the passivation is furthermore demonstrated with homogenously passivated devices reaching certified efficiencies of 28.9% for an active area of 60 cm².