Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction

Handle URI:
http://hdl.handle.net/10754/627587
Title:
Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction
Authors:
Wang, Riming; Sun, Xiaohui; Ould-Chikh, Samy ( 0000-0002-3486-0944 ) ; Osadchii, Dmitrii; Bai, Fan; Kapteijn, Freek ( 0000-0003-0575-7953 ) ; Gascon, Jorge ( 0000-0001-7558-7123 )
Abstract:
A nitrogen-doped carbon was synthesized through the pyrolysis of the well-known metal-organic framework ZIF-8, followed by a subsequent acid treatment, and has been applied as a catalyst in the electrochemical reduction of carbon dioxide. The resulting electrode shows Faradaic efficiencies to carbon monoxide as high as ∼78%, with hydrogen being the only byproduct. The pyrolysis temperature determines the amount and the accessibility of N species in the carbon electrode, in which pyridinic-N and quaternary-N species play key roles in the selective formation of carbon monoxide.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical and Biological Engineering Program
Citation:
Wang R, Sun X, Ould-Chikh S, Osadchii D, Bai F, et al. (2018) Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.8b02226.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Applied Materials & Interfaces
Issue Date:
11-Apr-2018
DOI:
10.1021/acsami.8b02226
PubMed ID:
29638117
Type:
Article
ISSN:
1944-8244; 1944-8252
Sponsors:
The authors would like to thank the China Scholarship Council (CSC) for financial support.
Additional Links:
https://pubs.acs.org/doi/10.1021/acsami.8b02226
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical and Biological Engineering Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Rimingen
dc.contributor.authorSun, Xiaohuien
dc.contributor.authorOuld-Chikh, Samyen
dc.contributor.authorOsadchii, Dmitriien
dc.contributor.authorBai, Fanen
dc.contributor.authorKapteijn, Freeken
dc.contributor.authorGascon, Jorgeen
dc.date.accessioned2018-04-23T12:31:06Z-
dc.date.available2018-04-23T12:31:06Z-
dc.date.issued2018-04-11en
dc.identifier.citationWang R, Sun X, Ould-Chikh S, Osadchii D, Bai F, et al. (2018) Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.8b02226.en
dc.identifier.issn1944-8244en
dc.identifier.issn1944-8252en
dc.identifier.pmid29638117-
dc.identifier.doi10.1021/acsami.8b02226en
dc.identifier.urihttp://hdl.handle.net/10754/627587-
dc.description.abstractA nitrogen-doped carbon was synthesized through the pyrolysis of the well-known metal-organic framework ZIF-8, followed by a subsequent acid treatment, and has been applied as a catalyst in the electrochemical reduction of carbon dioxide. The resulting electrode shows Faradaic efficiencies to carbon monoxide as high as ∼78%, with hydrogen being the only byproduct. The pyrolysis temperature determines the amount and the accessibility of N species in the carbon electrode, in which pyridinic-N and quaternary-N species play key roles in the selective formation of carbon monoxide.en
dc.description.sponsorshipThe authors would like to thank the China Scholarship Council (CSC) for financial support.en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acsami.8b02226en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acsami.8b02226.en
dc.subjectElectrocatalysten
dc.subjectNitrogen-doped Carbonen
dc.subjectZif-8en
dc.subjectCo2 Electrochemical Reductionen
dc.subjectMof-mediated Synthesisen
dc.titleMetal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reductionen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical and Biological Engineering Programen
dc.identifier.journalACS Applied Materials & Interfacesen
dc.eprint.versionPost-printen
dc.contributor.institutionCatalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlandsen
kaust.authorOuld-Chikh, Samyen
kaust.authorGascon, Jorgeen

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