Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

Handle URI:
http://hdl.handle.net/10754/627385
Title:
Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst
Authors:
Ghorpade, Seema Arun; Sawant, Dinesh N; Renn, Dominik; Zernickel, Anna ( 0000-0002-0567-2979 ) ; Du, Weiyuan; Sekar, Nethi; Eppinger, Jorg ( 0000-0001-7886-7059 )
Abstract:
Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; Bioscience Program; KAUST Solar Center (KSC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)
Citation:
Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
New Journal of Chemistry
KAUST Grant Number:
FIC/2010/07
Issue Date:
19-Mar-2018
DOI:
10.1039/c8nj00660a
Type:
Article
ISSN:
1144-0546; 1369-9261
Sponsors:
The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C8NJ00660A#!divAbstract
Appears in Collections:
Articles; Bioscience Program; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorGhorpade, Seema Arunen
dc.contributor.authorSawant, Dinesh Nen
dc.contributor.authorRenn, Dominiken
dc.contributor.authorZernickel, Annaen
dc.contributor.authorDu, Weiyuanen
dc.contributor.authorSekar, Nethien
dc.contributor.authorEppinger, Jorgen
dc.date.accessioned2018-04-01T08:20:27Z-
dc.date.available2018-04-01T08:20:27Z-
dc.date.issued2018-03-19en
dc.identifier.citationGhorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.en
dc.identifier.issn1144-0546en
dc.identifier.issn1369-9261en
dc.identifier.doi10.1039/c8nj00660aen
dc.identifier.urihttp://hdl.handle.net/10754/627385-
dc.description.abstractAllylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.en
dc.description.sponsorshipThe author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C8NJ00660A#!divAbstracten
dc.rightsArchived with thanks to New Journal of Chemistryen
dc.titleAqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalysten
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentBioscience Programen
dc.contributor.departmentKAUST Solar Center (KSC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalNew Journal of Chemistryen
dc.eprint.versionPost-printen
dc.contributor.institutionDepartment of Dyestuff Technology, Institute of Chemical Technology (Deemed University), N. Parekh Marg, Matunga, Mumbai-400019, Maharashtra, India.en
kaust.authorGhorpade, Seema Arunen
kaust.authorSawant, Dinesh Nen
kaust.authorRenn, Dominiken
kaust.authorZernickel, Annaen
kaust.authorDu, Weiyuanen
kaust.authorEppinger, Jorgen
kaust.grant.numberFIC/2010/07en
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