Hydrogen generation from formic acid catalyzed by a metal complex under amine-free and aqueous conditions

Handle URI:
http://hdl.handle.net/10754/627081
Title:
Hydrogen generation from formic acid catalyzed by a metal complex under amine-free and aqueous conditions
Authors:
Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Guan, Chao; Pan, Yupeng; Hu, Jinsong; Li, Huaifeng ( 0000-0001-9661-803X )
Assignee:
King Abdullah University Of Science And Technology
Abstract:
The present invention provides a class of catalyst compounds that can safely and effectively release hydrogen gas from a chemical substrate without producing either noxious byproducts or byproducts that will deactivate the catalyst. The present invention provides catalysts used to produce hydrogen that has a satisfactory and sufficient lifespan (measured by turnover number (TON)), that has stability in the presence of moisture, air, acid, or impurities, promote a rapid reaction rate, and remain stable under the reaction conditions required for an effective hydrogen production system. Described herein are compounds for use as catalysts, as well as methods for producing hydrogen from formic acid and/or a formate using the disclosed catalysts. The methods include contacting formic acid and/or a formate with a catalyst as described herein, as well as methods of producing formic acid and/or a formate using the disclosed catalyst and methods for generating electricity using the catalysts described herein.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)
Issue Date:
4-Jan-2018
Submitted date:
2016-06-29
Type:
Patent
Application Number:
WO 2018002850 A1
Patent Status:
Published Application
Additional Links:
http://www.google.com/patents/WO2018002850A1; http://worldwide.espacenet.com/publicationDetails/biblio?CC=WO&NR=2018002850A1&KC=A1&FT=D
Appears in Collections:
Patents

Full metadata record

DC FieldValue Language
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorGuan, Chaoen
dc.contributor.authorPan, Yupengen
dc.contributor.authorHu, Jinsongen
dc.contributor.authorLi, Huaifengen
dc.date.accessioned2018-02-12T09:40:27Z-
dc.date.available2018-02-12T09:40:27Z-
dc.date.issued2018-01-04-
dc.date.submitted2016-06-29-
dc.identifier.urihttp://hdl.handle.net/10754/627081-
dc.description.abstractThe present invention provides a class of catalyst compounds that can safely and effectively release hydrogen gas from a chemical substrate without producing either noxious byproducts or byproducts that will deactivate the catalyst. The present invention provides catalysts used to produce hydrogen that has a satisfactory and sufficient lifespan (measured by turnover number (TON)), that has stability in the presence of moisture, air, acid, or impurities, promote a rapid reaction rate, and remain stable under the reaction conditions required for an effective hydrogen production system. Described herein are compounds for use as catalysts, as well as methods for producing hydrogen from formic acid and/or a formate using the disclosed catalysts. The methods include contacting formic acid and/or a formate with a catalyst as described herein, as well as methods of producing formic acid and/or a formate using the disclosed catalyst and methods for generating electricity using the catalysts described herein.en
dc.relation.urlhttp://www.google.com/patents/WO2018002850A1en
dc.relation.urlhttp://worldwide.espacenet.com/publicationDetails/biblio?CC=WO&NR=2018002850A1&KC=A1&FT=Den
dc.titleHydrogen generation from formic acid catalyzed by a metal complex under amine-free and aqueous conditionsen
dc.typePatenten
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.description.statusPublished Applicationen
dc.contributor.assigneeKing Abdullah University Of Science And Technologyen
dc.description.countryWorld Intellectual Property Organization (WIPO)en
dc.identifier.applicationnumberWO 2018002850 A1en
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