One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks

Handle URI:
http://hdl.handle.net/10754/626807
Title:
One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks
Authors:
Wang, Xiaofang; Wang, Runwei; Liu, Xiaofang; Zhu, Pinwen; Qiu, Shilun
Abstract:
The in situ ligand 2,3-pyrazinedicarboxylic acid (2,3-H2pzdc) mixed with 1,1′-(1,4-butanediyl)bis(benzimidazole) (bbbi) is used to form two coordination polymers ([Cd(2,3-pzdc)(bbbi)] (1) and [Cd2Cl3(2-pzc)(bbbi)2] (2)) under hydrothermal conditions. Complex 1 was obtained in the absence of in situ reaction and 2 was synthesized with 2,3-H2pzdc in situ generating 2-pyrazinecarboxylate (2-pzc−). The structural details reveal that 1 has a 3D framework with dia topology, and 2 is a 2D layer structure and develops a 3D supramolecular structure via strong π⋯π stacking interactions. The ligand effects were compared for the two frameworks. In addition, fluorescence properties and thermal stabilities of 1 and 2 in the solid were studied.
Citation:
Wang X, Wang R, Liu X, Zhu P, Qiu S (2017) One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks. Journal of Coordination Chemistry 70: 3971–3981. Available: http://dx.doi.org/10.1080/00958972.2017.1408914.
Publisher:
Informa UK Limited
Journal:
Journal of Coordination Chemistry
KAUST Grant Number:
CRG-1-2012-LAI-009
Issue Date:
24-Dec-2017
DOI:
10.1080/00958972.2017.1408914
Type:
Article
ISSN:
0095-8972; 1029-0389
Sponsors:
This work was supported by the National Natural Science Foundation of China [grant number 21390394]; the National Basic Research Program of China [grant number 2012CB821700], [grant number 2011CB808703]; NSFC [grant number 21261130584], [grant number 91022030]; “111” project (B07016); Award Project of KAUST [grant number CRG-1-2012-LAI-009]; Ministry of Education, Science and Technology Development Center Project [grant number 20120061130012]; Science and Technology Research Program of the 13th Five Year Plan, Education Department of Jilin Province.
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Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Xiaofangen
dc.contributor.authorWang, Runweien
dc.contributor.authorLiu, Xiaofangen
dc.contributor.authorZhu, Pinwenen
dc.contributor.authorQiu, Shilunen
dc.date.accessioned2018-01-15T06:49:45Z-
dc.date.available2018-01-15T06:49:45Z-
dc.date.issued2017-12-24en
dc.identifier.citationWang X, Wang R, Liu X, Zhu P, Qiu S (2017) One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks. Journal of Coordination Chemistry 70: 3971–3981. Available: http://dx.doi.org/10.1080/00958972.2017.1408914.en
dc.identifier.issn0095-8972en
dc.identifier.issn1029-0389en
dc.identifier.doi10.1080/00958972.2017.1408914en
dc.identifier.urihttp://hdl.handle.net/10754/626807-
dc.description.abstractThe in situ ligand 2,3-pyrazinedicarboxylic acid (2,3-H2pzdc) mixed with 1,1′-(1,4-butanediyl)bis(benzimidazole) (bbbi) is used to form two coordination polymers ([Cd(2,3-pzdc)(bbbi)] (1) and [Cd2Cl3(2-pzc)(bbbi)2] (2)) under hydrothermal conditions. Complex 1 was obtained in the absence of in situ reaction and 2 was synthesized with 2,3-H2pzdc in situ generating 2-pyrazinecarboxylate (2-pzc−). The structural details reveal that 1 has a 3D framework with dia topology, and 2 is a 2D layer structure and develops a 3D supramolecular structure via strong π⋯π stacking interactions. The ligand effects were compared for the two frameworks. In addition, fluorescence properties and thermal stabilities of 1 and 2 in the solid were studied.en
dc.description.sponsorshipThis work was supported by the National Natural Science Foundation of China [grant number 21390394]; the National Basic Research Program of China [grant number 2012CB821700], [grant number 2011CB808703]; NSFC [grant number 21261130584], [grant number 91022030]; “111” project (B07016); Award Project of KAUST [grant number CRG-1-2012-LAI-009]; Ministry of Education, Science and Technology Development Center Project [grant number 20120061130012]; Science and Technology Research Program of the 13th Five Year Plan, Education Department of Jilin Province.en
dc.publisherInforma UK Limiteden
dc.subjectThe in situ reactionen
dc.subject2,3-pyrazinedicarboxylic aciden
dc.subjecthydrothermal synthesisen
dc.subjectluminescent propertyen
dc.titleOne ligand capable of in situ reaction in a mixed-ligand system with two new different frameworksen
dc.typeArticleen
dc.identifier.journalJournal of Coordination Chemistryen
dc.contributor.institutionState Key Laboratory of Titanium Vanadium Detection, Panzhihua University, Panzhihua, Chinaen
dc.contributor.institutionJilin University, Changchun, Chinaen
kaust.grant.numberCRG-1-2012-LAI-009en
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