Facile Synthesis of Highly Water-Soluble Lanthanide-Doped t-LaVO4 NPs for Antifake Ink and Latent Fingermark Detection

Handle URI:
http://hdl.handle.net/10754/626576
Title:
Facile Synthesis of Highly Water-Soluble Lanthanide-Doped t-LaVO4 NPs for Antifake Ink and Latent Fingermark Detection
Authors:
Chen, Cailing; Yu, Ying; Li, Chunguang; Liu, Dan; Huang, He; Liang, Chen; Lou, Yue; Han, Yu ( 0000-0003-1462-1118 ) ; Shi, Zhan; Feng, Shouhua
Abstract:
In the information age, it is important to protect the security and integrity of the information. As a result, the fluorescent ink as an antifake technology and the fingermark as an information carrier have aroused great interest. In this work, highly water-soluble lanthanide (Ln3+ )-doped tetragonal phase (t-) LaVO4 nanoparticles (NPs) are successfully obtained via a simple, fast, and green microwave-assisted hydrothermal method. The average size of t-LaVO4 NPs is about 43 nm. The aqueous solutions of Ln3+ -doped t-LaVO4 exhibit excellent fluorescence properties under ultraviolet light (UV) excitation (t-LaVO4 :10%Eu is bright red and t-LaVO4 :0.5%Dy is close to white). Some superb antifake fluorescent patterns are printed using Ln3+ -doped t-LaVO4 aqueous solution as ink, which indicates the as-prepared Ln3+ -doped t-LaVO4 NPs as fluorescent ink can meet the various antifake requirements. Notably, the designed convenient antifake fluorescent codes with improved security could be directly scanned and decoded by a smart phone. What's more, the as-prepared NPs can be used for the development of latent fingermark on various substrates and the second-level detail information can be clearly obtained from the magnification of a fingermark. These results indicate that the as-prepared Ln3+ -doped t-LaVO4 fluorescent NPs have great potential in security application.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division
Citation:
Chen C, Yu Y, Li C, Liu D, Huang H, et al. (2017) Facile Synthesis of Highly Water-Soluble Lanthanide-Doped t-LaVO4 NPs for Antifake Ink and Latent Fingermark Detection. Small 13: 1702305. Available: http://dx.doi.org/10.1002/smll.201702305.
Publisher:
Wiley-Blackwell
Journal:
Small
Issue Date:
8-Nov-2017
DOI:
10.1002/smll.201702305
Type:
Article
ISSN:
1613-6810
Sponsors:
C.C. and Y.Y. contributed equally to this work. This work was supported by the Foundation of the Natural Science Foundation of China (Nos. 21621001 and 21371069), the National Key Research and Development Program of China (No. 2016YFB0701100), the 111 project (No. B17020), the S&T Development Program of Jilin Province of China (No. 20160101325JC). The authors also gratefully acknowledge the financial support from the Natural Science Foundation of China through Research Fund for International Young Scientists scheme (No. 21550110190).
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/smll.201702305/full
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Cailingen
dc.contributor.authorYu, Yingen
dc.contributor.authorLi, Chunguangen
dc.contributor.authorLiu, Danen
dc.contributor.authorHuang, Heen
dc.contributor.authorLiang, Chenen
dc.contributor.authorLou, Yueen
dc.contributor.authorHan, Yuen
dc.contributor.authorShi, Zhanen
dc.contributor.authorFeng, Shouhuaen
dc.date.accessioned2018-01-01T12:19:00Z-
dc.date.available2018-01-01T12:19:00Z-
dc.date.issued2017-11-08en
dc.identifier.citationChen C, Yu Y, Li C, Liu D, Huang H, et al. (2017) Facile Synthesis of Highly Water-Soluble Lanthanide-Doped t-LaVO4 NPs for Antifake Ink and Latent Fingermark Detection. Small 13: 1702305. Available: http://dx.doi.org/10.1002/smll.201702305.en
dc.identifier.issn1613-6810en
dc.identifier.doi10.1002/smll.201702305en
dc.identifier.urihttp://hdl.handle.net/10754/626576-
dc.description.abstractIn the information age, it is important to protect the security and integrity of the information. As a result, the fluorescent ink as an antifake technology and the fingermark as an information carrier have aroused great interest. In this work, highly water-soluble lanthanide (Ln3+ )-doped tetragonal phase (t-) LaVO4 nanoparticles (NPs) are successfully obtained via a simple, fast, and green microwave-assisted hydrothermal method. The average size of t-LaVO4 NPs is about 43 nm. The aqueous solutions of Ln3+ -doped t-LaVO4 exhibit excellent fluorescence properties under ultraviolet light (UV) excitation (t-LaVO4 :10%Eu is bright red and t-LaVO4 :0.5%Dy is close to white). Some superb antifake fluorescent patterns are printed using Ln3+ -doped t-LaVO4 aqueous solution as ink, which indicates the as-prepared Ln3+ -doped t-LaVO4 NPs as fluorescent ink can meet the various antifake requirements. Notably, the designed convenient antifake fluorescent codes with improved security could be directly scanned and decoded by a smart phone. What's more, the as-prepared NPs can be used for the development of latent fingermark on various substrates and the second-level detail information can be clearly obtained from the magnification of a fingermark. These results indicate that the as-prepared Ln3+ -doped t-LaVO4 fluorescent NPs have great potential in security application.en
dc.description.sponsorshipC.C. and Y.Y. contributed equally to this work. This work was supported by the Foundation of the Natural Science Foundation of China (Nos. 21621001 and 21371069), the National Key Research and Development Program of China (No. 2016YFB0701100), the 111 project (No. B17020), the S&T Development Program of Jilin Province of China (No. 20160101325JC). The authors also gratefully acknowledge the financial support from the Natural Science Foundation of China through Research Fund for International Young Scientists scheme (No. 21550110190).en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/smll.201702305/fullen
dc.subjectFluorescenceen
dc.subjectLatent Fingermarken
dc.subjectMicrowave-assisted Hydrothermalen
dc.subjectAntifake Inken
dc.subjectLanthanide-doped Nanoparticleen
dc.titleFacile Synthesis of Highly Water-Soluble Lanthanide-Doped t-LaVO4 NPs for Antifake Ink and Latent Fingermark Detectionen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalSmallen
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry; College of Chemistry; Jilin University; Changchun 130022 P. R. Chinaen
dc.contributor.institutionState Key Laboratory of Rare Earth Resource; Utilization Changchun Institute of Applied Chemistry; Chinese Academy of Sciences; Changchun 130012 P. R. Chinaen
kaust.authorHan, Yuen
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