Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis

Handle URI:
http://hdl.handle.net/10754/626369
Title:
Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis
Authors:
Yue, Huifeng; Zhu, Chen; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
An efficient photoredox/nickel dual catalyzed sulfonylation reaction of aryl, heteroaryl, and vinyl halides has been achieved for the first time. This newly developed sulfonylation protocol provides a versatile method for the synthesis of diverse aromatic sulfones at room temperature and shows excellent functional group tolerance. The electrophilic coupling partners are not limited to aryl, heteroaryl and vinyl bromides but also less reactive aryl chlorides are suitable substrates for this transformation.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Yue H, Zhu C, Rueping M (2017) Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201711104.
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
6-Dec-2017
DOI:
10.1002/anie.201711104; 10.1002/ange.201711104
Type:
Article
ISSN:
1433-7851
Sponsors:
H.Y. acknowledges the China Scholarship Council. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) / ERC Grant Agreement no. 617044 (SunCatChem).
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201711104/abstract
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorYue, Huifengen
dc.contributor.authorZhu, Chenen
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2017-12-14T12:34:04Z-
dc.date.available2017-12-14T12:34:04Z-
dc.date.issued2017-12-06en
dc.identifier.citationYue H, Zhu C, Rueping M (2017) Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201711104.en
dc.identifier.issn1433-7851en
dc.identifier.doi10.1002/anie.201711104en
dc.identifier.doi10.1002/ange.201711104en
dc.identifier.urihttp://hdl.handle.net/10754/626369-
dc.description.abstractAn efficient photoredox/nickel dual catalyzed sulfonylation reaction of aryl, heteroaryl, and vinyl halides has been achieved for the first time. This newly developed sulfonylation protocol provides a versatile method for the synthesis of diverse aromatic sulfones at room temperature and shows excellent functional group tolerance. The electrophilic coupling partners are not limited to aryl, heteroaryl and vinyl bromides but also less reactive aryl chlorides are suitable substrates for this transformation.en
dc.description.sponsorshipH.Y. acknowledges the China Scholarship Council. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) / ERC Grant Agreement no. 617044 (SunCatChem).en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/anie.201711104/abstracten
dc.rightsThis is the peer reviewed version of the following article: Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis, which has been published in final form at http://doi.org/10.1002/anie.201711104. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.en
dc.titleCross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysisen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAngewandte Chemie International Editionen
dc.eprint.versionPost-printen
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, Germanyen
kaust.authorRueping, Magnusen
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