Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

Handle URI:
http://hdl.handle.net/10754/626330
Title:
Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate
Authors:
Ghorpade, Seema Arun; Sawant, Dinesh N; Makki, Arwa ( 0000-0002-5540-0162 ) ; Sekar, N; Eppinger, Jorg ( 0000-0001-7886-7059 )
Abstract:
Transition metal free, water based, greener protocol for allylic alkylation, allylic amination, O-allylation of (E)-1,3-diphenylallyl acetate is described. The developed methodology is applicable for a wide range of nucleophiles furnishing excellent yields of corresponding products up to 87% under mild reaction conditions. A Distinct effect of water and base is explored for allylic nucleophilic substitution reactions of (E)-1,3-diphenylallyl acetate.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Ghorpade SA, Sawant DN, Makki A, Sekar N, Eppinger J (2017) Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate. Green Chemistry. Available: http://dx.doi.org/10.1039/c7gc03123h.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Green Chemistry
KAUST Grant Number:
FIC/2010/07
Issue Date:
30-Nov-2017
DOI:
10.1039/c7gc03123h
Type:
Article
ISSN:
1463-9262; 1463-9270
Sponsors:
The author Seema Arun Ghorpade is thankful to the Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship and Institute of Chemical Technology, Matunga, Mumbai. This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). All authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC03123H#!divAbstract
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorGhorpade, Seema Arunen
dc.contributor.authorSawant, Dinesh Nen
dc.contributor.authorMakki, Arwaen
dc.contributor.authorSekar, Nen
dc.contributor.authorEppinger, Jorgen
dc.date.accessioned2017-12-07T13:16:39Z-
dc.date.available2017-12-07T13:16:39Z-
dc.date.issued2017-11-30en
dc.identifier.citationGhorpade SA, Sawant DN, Makki A, Sekar N, Eppinger J (2017) Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate. Green Chemistry. Available: http://dx.doi.org/10.1039/c7gc03123h.en
dc.identifier.issn1463-9262en
dc.identifier.issn1463-9270en
dc.identifier.doi10.1039/c7gc03123hen
dc.identifier.urihttp://hdl.handle.net/10754/626330-
dc.description.abstractTransition metal free, water based, greener protocol for allylic alkylation, allylic amination, O-allylation of (E)-1,3-diphenylallyl acetate is described. The developed methodology is applicable for a wide range of nucleophiles furnishing excellent yields of corresponding products up to 87% under mild reaction conditions. A Distinct effect of water and base is explored for allylic nucleophilic substitution reactions of (E)-1,3-diphenylallyl acetate.en
dc.description.sponsorshipThe author Seema Arun Ghorpade is thankful to the Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship and Institute of Chemical Technology, Matunga, Mumbai. This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). All authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC03123H#!divAbstracten
dc.rightsArchived with thanks to Green Chemistryen
dc.titleWater promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetateen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalGreen Chemistryen
dc.eprint.versionPost-printen
dc.contributor.institutionDepartment of Dyestuff Technology, Institute of Chemical Technology (Deemed University), N. Parekh Marg, Matunga, Mumbai-400019, Maharashtra, India.en
kaust.authorGhorpade, Seema Arunen
kaust.authorSawant, Dinesh Nen
kaust.authorMakki, Arwaen
kaust.authorEppinger, Jorgen
kaust.grant.numberFIC/2010/07en
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.