Facial One-Pot Synthesis of D 3h Symmetric Bicyclocalix[2]arene[2]triazines and Their Layered Comb Self-Assembly

Handle URI:
http://hdl.handle.net/10754/626234
Title:
Facial One-Pot Synthesis of D 3h Symmetric Bicyclocalix[2]arene[2]triazines and Their Layered Comb Self-Assembly
Authors:
Chen, Yin; Jiahui, Wang; Xu, Hai; Qianqian, Li; Jing, Jiang
Abstract:
A number of D3h symmetric bicyclocalix[2]arene[2]triazine core compounds were synthesized via a general and good-yielding (43-48% yield) facile protocol starting from cyanuric halides, phloroglucinol and K2CO3 under very mild reaction conditions. These cage-like compounds are tolerate with different reaction conditions and can be derived with other functional groups in high yield. The X-ray crystal structures show these compounds have slightly distorted D3h symmetric structures. Due to the unique molecular topological structure, bicyclocalix[2]arene[2]triazine molecules form unique layered comb networks when hydrogen bond groups exist (such as CO2H, B(OH)2), which represent a new kind of building block unit for supramolecular architectures.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Chen Y, Jiahui W, Xu H, Qianqian L, Jing J (2017) Facial one-pot synthesis of D 3h symmetric bicyclocalix[2]arene[2]triazines and their layered comb self-assembly. Journal of Saudi Chemical Society. Available: http://dx.doi.org/10.1016/j.jscs.2017.11.003.
Publisher:
Elsevier BV
Journal:
Journal of Saudi Chemical Society
Issue Date:
23-Nov-2017
DOI:
10.1016/j.jscs.2017.11.003
Type:
Article
ISSN:
1319-6103
Additional Links:
http://www.sciencedirect.com/science/article/pii/S1319610317301370
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Yinen
dc.contributor.authorJiahui, Wangen
dc.contributor.authorXu, Haien
dc.contributor.authorQianqian, Lien
dc.contributor.authorJing, Jiangen
dc.date.accessioned2017-11-29T11:13:55Z-
dc.date.available2017-11-29T11:13:55Z-
dc.date.issued2017-11-23en
dc.identifier.citationChen Y, Jiahui W, Xu H, Qianqian L, Jing J (2017) Facial one-pot synthesis of D 3h symmetric bicyclocalix[2]arene[2]triazines and their layered comb self-assembly. Journal of Saudi Chemical Society. Available: http://dx.doi.org/10.1016/j.jscs.2017.11.003.en
dc.identifier.issn1319-6103en
dc.identifier.doi10.1016/j.jscs.2017.11.003en
dc.identifier.urihttp://hdl.handle.net/10754/626234-
dc.description.abstractA number of D3h symmetric bicyclocalix[2]arene[2]triazine core compounds were synthesized via a general and good-yielding (43-48% yield) facile protocol starting from cyanuric halides, phloroglucinol and K2CO3 under very mild reaction conditions. These cage-like compounds are tolerate with different reaction conditions and can be derived with other functional groups in high yield. The X-ray crystal structures show these compounds have slightly distorted D3h symmetric structures. Due to the unique molecular topological structure, bicyclocalix[2]arene[2]triazine molecules form unique layered comb networks when hydrogen bond groups exist (such as CO2H, B(OH)2), which represent a new kind of building block unit for supramolecular architectures.en
dc.publisherElsevier BVen
dc.relation.urlhttp://www.sciencedirect.com/science/article/pii/S1319610317301370en
dc.rights© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleFacial One-Pot Synthesis of D 3h Symmetric Bicyclocalix[2]arene[2]triazines and Their Layered Comb Self-Assemblyen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalJournal of Saudi Chemical Societyen
dc.eprint.versionPost-printen
dc.contributor.institutionCent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Chinaen
kaust.authorChen, Yinen
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