Handle URI:
http://hdl.handle.net/10754/626075
Title:
Designing solid-liquid interphases for sodium batteries
Authors:
Choudhury, Snehashis; Wei, Shuya; Ozhabes, Yalcin; Gunceler, Deniz; Zachman, Michael J.; Tu, Zhengyuan; Shin, Jung Hwan; Nath, Pooja; Agrawal, Akanksha; Kourkoutis, Lena F.; Arias, Tomas A.; Archer, Lynden A.
Abstract:
Secondary batteries based on earth-abundant sodium metal anodes are desirable for both stationary and portable electrical energy storage. Room-temperature sodium metal batteries are impractical today because morphological instability during recharge drives rough, dendritic electrodeposition. Chemical instability of liquid electrolytes also leads to premature cell failure as a result of parasitic reactions with the anode. Here we use joint density-functional theoretical analysis to show that the surface diffusion barrier for sodium ion transport is a sensitive function of the chemistry of solid–electrolyte interphase. In particular, we find that a sodium bromide interphase presents an exceptionally low energy barrier to ion transport, comparable to that of metallic magnesium. We evaluate this prediction by means of electrochemical measurements and direct visualization studies. These experiments reveal an approximately three-fold reduction in activation energy for ion transport at a sodium bromide interphase. Direct visualization of sodium electrodeposition confirms large improvements in stability of sodium deposition at sodium bromide-rich interphases.
Citation:
Choudhury S, Wei S, Ozhabes Y, Gunceler D, Zachman MJ, et al. (2017) Designing solid-liquid interphases for sodium batteries. Nature Communications 8. Available: http://dx.doi.org/10.1038/s41467-017-00742-x.
Publisher:
Springer Nature
Journal:
Nature Communications
KAUST Grant Number:
KUS-C1-018-02
Issue Date:
6-Oct-2017
DOI:
10.1038/s41467-017-00742-x
Type:
Article
ISSN:
2041-1723
Sponsors:
This work was supported by the Department of Energy, Advanced Research Projects Agency—Energy (ARPA-E) through award #DE-AR0000750. The work made use of electrochemical characterization facilities in the KAUST-CU Center for Energy and Sustainability, supported by the King Abdullah University of Science and Technology (KAUST) through Award # KUS-C1-018-02. Electron microscopy facilities at the Cornell Center for Materials Research (CCMR), an NSF-supported MRSEC through Grant DMR-1120296, were also used for the study. M.J.Z. and L.F.K. acknowledge support by the NSF (DMR-1654596).
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Full metadata record

DC FieldValue Language
dc.contributor.authorChoudhury, Snehashisen
dc.contributor.authorWei, Shuyaen
dc.contributor.authorOzhabes, Yalcinen
dc.contributor.authorGunceler, Denizen
dc.contributor.authorZachman, Michael J.en
dc.contributor.authorTu, Zhengyuanen
dc.contributor.authorShin, Jung Hwanen
dc.contributor.authorNath, Poojaen
dc.contributor.authorAgrawal, Akankshaen
dc.contributor.authorKourkoutis, Lena F.en
dc.contributor.authorArias, Tomas A.en
dc.contributor.authorArcher, Lynden A.en
dc.date.accessioned2017-11-01T08:19:11Z-
dc.date.available2017-11-01T08:19:11Z-
dc.date.issued2017-10-06en
dc.identifier.citationChoudhury S, Wei S, Ozhabes Y, Gunceler D, Zachman MJ, et al. (2017) Designing solid-liquid interphases for sodium batteries. Nature Communications 8. Available: http://dx.doi.org/10.1038/s41467-017-00742-x.en
dc.identifier.issn2041-1723en
dc.identifier.doi10.1038/s41467-017-00742-xen
dc.identifier.urihttp://hdl.handle.net/10754/626075-
dc.description.abstractSecondary batteries based on earth-abundant sodium metal anodes are desirable for both stationary and portable electrical energy storage. Room-temperature sodium metal batteries are impractical today because morphological instability during recharge drives rough, dendritic electrodeposition. Chemical instability of liquid electrolytes also leads to premature cell failure as a result of parasitic reactions with the anode. Here we use joint density-functional theoretical analysis to show that the surface diffusion barrier for sodium ion transport is a sensitive function of the chemistry of solid–electrolyte interphase. In particular, we find that a sodium bromide interphase presents an exceptionally low energy barrier to ion transport, comparable to that of metallic magnesium. We evaluate this prediction by means of electrochemical measurements and direct visualization studies. These experiments reveal an approximately three-fold reduction in activation energy for ion transport at a sodium bromide interphase. Direct visualization of sodium electrodeposition confirms large improvements in stability of sodium deposition at sodium bromide-rich interphases.en
dc.description.sponsorshipThis work was supported by the Department of Energy, Advanced Research Projects Agency—Energy (ARPA-E) through award #DE-AR0000750. The work made use of electrochemical characterization facilities in the KAUST-CU Center for Energy and Sustainability, supported by the King Abdullah University of Science and Technology (KAUST) through Award # KUS-C1-018-02. Electron microscopy facilities at the Cornell Center for Materials Research (CCMR), an NSF-supported MRSEC through Grant DMR-1120296, were also used for the study. M.J.Z. and L.F.K. acknowledge support by the NSF (DMR-1654596).en
dc.publisherSpringer Natureen
dc.titleDesigning solid-liquid interphases for sodium batteriesen
dc.typeArticleen
dc.identifier.journalNature Communicationsen
dc.contributor.institutionSchool of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY, 14853, USAen
dc.contributor.institutionDepartment of Physics, Cornell University, Ithaca, NY, 14853, USAen
dc.contributor.institutionSchool of Applied and Engineering Physics, Cornell University, Ithaca, NY, 14853, USAen
dc.contributor.institutionDepartment of Materials Science and Engineering, Cornell University, Ithaca, NY, 14853, USAen
dc.contributor.institutionKavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, NY, 14853, USAen
kaust.grant.numberKUS-C1-018-02en
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