Manganese-Catalyzed C−H Functionalizations: Hydroarylations and Alkenylations Involving an Unexpected Heteroaryl Shift

Handle URI:
http://hdl.handle.net/10754/625988
Title:
Manganese-Catalyzed C−H Functionalizations: Hydroarylations and Alkenylations Involving an Unexpected Heteroaryl Shift
Authors:
Wang, Chengming; Wang, Ai; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
A manganese-catalyzed regio- and stereoselective hydroarylation of allenes is reported. The C−H functionalization method provides access to various alkenylated indoles in excellent yields. Moreover, a hydroarylation/cyclization cascade involving an unexpected C−N bond cleavage and aryl shift has been developed, which provides a new synthetic approach to substituted pyrroloindolones.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Wang C, Wang A, Rueping M (2017) Manganese-Catalyzed C−H Functionalizations: Hydroarylations and Alkenylations Involving an Unexpected Heteroaryl Shift. Angewandte Chemie 129: 10067–10070. Available: http://dx.doi.org/10.1002/ange.201704682.
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie
Issue Date:
24-Jun-2017
DOI:
10.1002/ange.201704682; 10.1002/anie.201704682
Type:
Article
ISSN:
0044-8249
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/ange.201704682/full
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Chengmingen
dc.contributor.authorWang, Aien
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2017-10-30T08:39:48Z-
dc.date.available2017-10-30T08:39:48Z-
dc.date.issued2017-06-24en
dc.identifier.citationWang C, Wang A, Rueping M (2017) Manganese-Catalyzed C−H Functionalizations: Hydroarylations and Alkenylations Involving an Unexpected Heteroaryl Shift. Angewandte Chemie 129: 10067–10070. Available: http://dx.doi.org/10.1002/ange.201704682.en
dc.identifier.issn0044-8249en
dc.identifier.doi10.1002/ange.201704682en
dc.identifier.doi10.1002/anie.201704682en
dc.identifier.urihttp://hdl.handle.net/10754/625988-
dc.description.abstractA manganese-catalyzed regio- and stereoselective hydroarylation of allenes is reported. The C−H functionalization method provides access to various alkenylated indoles in excellent yields. Moreover, a hydroarylation/cyclization cascade involving an unexpected C−N bond cleavage and aryl shift has been developed, which provides a new synthetic approach to substituted pyrroloindolones.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/ange.201704682/fullen
dc.titleManganese-Catalyzed C−H Functionalizations: Hydroarylations and Alkenylations Involving an Unexpected Heteroaryl Shiften
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAngewandte Chemieen
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen; Landoltweg 1 52074 Aachen Germanyen
dc.contributor.institutionInstitute of Inorganic Chemistry; RWTH Aachen; Landoltweg 1 52074 Aachen Germanyen
kaust.authorRueping, Magnusen
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