Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents

Handle URI:
http://hdl.handle.net/10754/625745
Title:
Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents
Authors:
Adil, Karim ( 0000-0002-3804-1065 ) ; Bhatt, Prashant; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Abtab, Sk Md Towsif; Jiang, Hao; Assen, Ayalew H.; Mallick, Arijit; Cadiau, Amandine ( 0000-0002-3036-9197 ) ; Aqil, Jamal; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
The development of practical solutions for the energy-efficient capture of carbon dioxide is of prime importance and continues to attract intensive research interest. Conceivably, the implementation of adsorption-based processes using different cycling modes, e.g., pressure-swing adsorption or temperature-swing adsorption, offers great prospects to address this challenge. Practically, the successful deployment of practical adsorption-based technologies depends on the development of made-to-order adsorbents expressing mutually two compulsory requisites: i) high selectivity/affinity for CO2 and ii) excellent chemical stability in the presence of impurities. This study presents a new comprehensive experimental protocol apposite for assessing the prospects of a given physical adsorbent for carbon capture under flue gas stream conditions. The protocol permits: i) the baseline performance of commercial adsorbents such as zeolite 13X, activated carbon versus liquid amine scrubbing to be ascertained, and ii) a standardized evaluation of the best reported metal-organic framework (MOF) materials for carbon dioxide capture from flue gas to be undertaken. This extensive study corroborates the exceptional CO2 capture performance of the recently isolated second-generation fluorinated MOF material, NbOFFIVE-1-Ni, concomitant with an impressive chemical stability and a low energy for regeneration. Essentially, the NbOFFIVE-1-Ni adsorbent presents the best compromise by satisfying all the required metrics for efficient CO2 scrubbing.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division
Citation:
Adil K, Bhatt PM, Belmabkhout Y, Abtab SMT, Jiang H, et al. (2017) Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents. Advanced Materials: 1702953. Available: http://dx.doi.org/10.1002/adma.201702953.
Publisher:
Wiley-Blackwell
Journal:
Advanced Materials
Issue Date:
22-Aug-2017
DOI:
10.1002/adma.201702953
Type:
Article
ISSN:
0935-9648
Sponsors:
K.A. and P.M.B. contributed equally to this work. This research was financed by ARAMCO.
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/adma.201702953/full
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorAdil, Karimen
dc.contributor.authorBhatt, Prashanten
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorAbtab, Sk Md Towsifen
dc.contributor.authorJiang, Haoen
dc.contributor.authorAssen, Ayalew H.en
dc.contributor.authorMallick, Arijiten
dc.contributor.authorCadiau, Amandineen
dc.contributor.authorAqil, Jamalen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2017-10-03T12:49:37Z-
dc.date.available2017-10-03T12:49:37Z-
dc.date.issued2017-08-22en
dc.identifier.citationAdil K, Bhatt PM, Belmabkhout Y, Abtab SMT, Jiang H, et al. (2017) Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents. Advanced Materials: 1702953. Available: http://dx.doi.org/10.1002/adma.201702953.en
dc.identifier.issn0935-9648en
dc.identifier.doi10.1002/adma.201702953en
dc.identifier.urihttp://hdl.handle.net/10754/625745-
dc.description.abstractThe development of practical solutions for the energy-efficient capture of carbon dioxide is of prime importance and continues to attract intensive research interest. Conceivably, the implementation of adsorption-based processes using different cycling modes, e.g., pressure-swing adsorption or temperature-swing adsorption, offers great prospects to address this challenge. Practically, the successful deployment of practical adsorption-based technologies depends on the development of made-to-order adsorbents expressing mutually two compulsory requisites: i) high selectivity/affinity for CO2 and ii) excellent chemical stability in the presence of impurities. This study presents a new comprehensive experimental protocol apposite for assessing the prospects of a given physical adsorbent for carbon capture under flue gas stream conditions. The protocol permits: i) the baseline performance of commercial adsorbents such as zeolite 13X, activated carbon versus liquid amine scrubbing to be ascertained, and ii) a standardized evaluation of the best reported metal-organic framework (MOF) materials for carbon dioxide capture from flue gas to be undertaken. This extensive study corroborates the exceptional CO2 capture performance of the recently isolated second-generation fluorinated MOF material, NbOFFIVE-1-Ni, concomitant with an impressive chemical stability and a low energy for regeneration. Essentially, the NbOFFIVE-1-Ni adsorbent presents the best compromise by satisfying all the required metrics for efficient CO2 scrubbing.en
dc.description.sponsorshipK.A. and P.M.B. contributed equally to this work. This research was financed by ARAMCO.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/adma.201702953/fullen
dc.subjectcarbon captureen
dc.subjectflue gasen
dc.subjectmetal–organic frameworksen
dc.titleValuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbentsen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalAdvanced Materialsen
dc.contributor.institutionARAMCO; R-GC 335, Floor 3, Research and Development Center, Bldg. 2297 Dhahran 31311 Kingdom of Saudi Arabiaen
kaust.authorAdil, Karimen
kaust.authorBhatt, Prashanten
kaust.authorBelmabkhout, Youssefen
kaust.authorAbtab, Sk Md Towsifen
kaust.authorJiang, Haoen
kaust.authorAssen, Ayalew H.en
kaust.authorMallick, Arijiten
kaust.authorCadiau, Amandineen
kaust.authorEddaoudi, Mohameden
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