Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal–Organic Squares

Handle URI:
http://hdl.handle.net/10754/625680
Title:
Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal–Organic Squares
Authors:
Wang, Shuang; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Cairns, Amy; Li, Guanghua ( 0000-0003-3029-8920 ) ; Huo, Qisheng; Liu, Yunling ( 0000-0001-5040-6816 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
A strategy based on metal-ligand directed assembly of metal-organic squares (MOSs), built-up from four-membered ring (4MR) secondary building units (SBUs), has been employed for the design and construction of isoreticular zeolite-like supramolecular assemblies (ZSAs). Four porous Co-based ZSAs having the same underlying gis topology, but differing only with respect to the capping and bridging linkers, were successfully isolated and fully characterized. In this series, each MOS in ZSA-3-ZSA-6 possess an ideal square geometry and is connected to four neighboring MOS via a total of 16 hydrogen bonds to give a 3-periodic porous network.To systematically assess the effect of the pore system (size and functionality) on the gas adsorption properties, we evaluated the MOSs for their affinity for different probe molecules such as CO2 and light hydrocarbons. ZSA-3-ZSA-6 showed high thermal stability (up to 300 °C) and was proven highly porous as evidenced by gas adsorption studies. Notably, alkyl-functionalized MOSs were found to offer potential for selective separation of CO2, C3H6, and C3H8 from CH4 and H2 containing gas stream, such as natural gas and refinery-off gases.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Wang S, Belmabkhout Y, Cairns AJ, Li G, Huo Q, et al. (2017) Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal–Organic Squares. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.7b06010.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Applied Materials & Interfaces
KAUST Grant Number:
FCC/1/1972-8-01
Issue Date:
11-Jul-2017
DOI:
10.1021/acsami.7b06010
Type:
Article
ISSN:
1944-8244; 1944-8252
Sponsors:
Research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST). M.E. and Y.B. gratefully acknowledge Internal KAUST FUND FCC/1/1972-8-01. We also gratefully acknowledge the financial support of the National Natural Science Foundation of China ( 21373095 and 21621001) and supported by the 111 Project (B17020).
Additional Links:
http://pubs.acs.org/doi/full/10.1021/acsami.7b06010
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Shuangen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorCairns, Amyen
dc.contributor.authorLi, Guanghuaen
dc.contributor.authorHuo, Qishengen
dc.contributor.authorLiu, Yunlingen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2017-10-03T12:49:33Z-
dc.date.available2017-10-03T12:49:33Z-
dc.date.issued2017-07-11en
dc.identifier.citationWang S, Belmabkhout Y, Cairns AJ, Li G, Huo Q, et al. (2017) Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal–Organic Squares. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.7b06010.en
dc.identifier.issn1944-8244en
dc.identifier.issn1944-8252en
dc.identifier.doi10.1021/acsami.7b06010en
dc.identifier.urihttp://hdl.handle.net/10754/625680-
dc.description.abstractA strategy based on metal-ligand directed assembly of metal-organic squares (MOSs), built-up from four-membered ring (4MR) secondary building units (SBUs), has been employed for the design and construction of isoreticular zeolite-like supramolecular assemblies (ZSAs). Four porous Co-based ZSAs having the same underlying gis topology, but differing only with respect to the capping and bridging linkers, were successfully isolated and fully characterized. In this series, each MOS in ZSA-3-ZSA-6 possess an ideal square geometry and is connected to four neighboring MOS via a total of 16 hydrogen bonds to give a 3-periodic porous network.To systematically assess the effect of the pore system (size and functionality) on the gas adsorption properties, we evaluated the MOSs for their affinity for different probe molecules such as CO2 and light hydrocarbons. ZSA-3-ZSA-6 showed high thermal stability (up to 300 °C) and was proven highly porous as evidenced by gas adsorption studies. Notably, alkyl-functionalized MOSs were found to offer potential for selective separation of CO2, C3H6, and C3H8 from CH4 and H2 containing gas stream, such as natural gas and refinery-off gases.en
dc.description.sponsorshipResearch reported in this publication was supported by King Abdullah University of Science and Technology (KAUST). M.E. and Y.B. gratefully acknowledge Internal KAUST FUND FCC/1/1972-8-01. We also gratefully acknowledge the financial support of the National Natural Science Foundation of China ( 21373095 and 21621001) and supported by the 111 Project (B17020).en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/full/10.1021/acsami.7b06010en
dc.subjectGas separationen
dc.subjectPorous Materialsen
dc.subjectMofsen
dc.subjectAlkyl-functionalizationen
dc.subjectMetal−organic Squaresen
dc.subjectZeolite-like Supramolecular Assembliesen
dc.titleTuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal–Organic Squaresen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalACS Applied Materials & Interfacesen
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. Chinaen
kaust.authorBelmabkhout, Youssefen
kaust.authorCairns, Amyen
kaust.authorEddaoudi, Mohameden
kaust.grant.numberFCC/1/1972-8-01en
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