A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis

Handle URI:
http://hdl.handle.net/10754/625243
Title:
A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis
Authors:
Bavykina, Anastasiya V.; Olivos Suarez, Alma Itzel; Osadchii, Dmitrii; Valecha, Rahul; Franz, Robert; Makkee, Michiel; Kapteijn, Freek; Gascon, Jorge
Abstract:
A quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Bavykina AV, Olivos Suarez AI, Osadchii D, Valecha R, Franz R, et al. (2017) A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.7b07339.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Applied Materials & Interfaces
Issue Date:
17-Jul-2017
DOI:
10.1021/acsami.7b07339
Type:
Article
ISSN:
1944-8244; 1944-8252
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/acsami.7b07339
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorBavykina, Anastasiya V.en
dc.contributor.authorOlivos Suarez, Alma Itzelen
dc.contributor.authorOsadchii, Dmitriien
dc.contributor.authorValecha, Rahulen
dc.contributor.authorFranz, Roberten
dc.contributor.authorMakkee, Michielen
dc.contributor.authorKapteijn, Freeken
dc.contributor.authorGascon, Jorgeen
dc.date.accessioned2017-07-26T06:19:08Z-
dc.date.available2017-07-26T06:19:08Z-
dc.date.issued2017-07-17en
dc.identifier.citationBavykina AV, Olivos Suarez AI, Osadchii D, Valecha R, Franz R, et al. (2017) A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis. ACS Applied Materials & Interfaces. Available: http://dx.doi.org/10.1021/acsami.7b07339.en
dc.identifier.issn1944-8244en
dc.identifier.issn1944-8252en
dc.identifier.doi10.1021/acsami.7b07339en
dc.identifier.urihttp://hdl.handle.net/10754/625243-
dc.description.abstractA quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acsami.7b07339en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acsami.7b07339.en
dc.subjectcovalent triazine frameworksen
dc.subjectstructured catalystsen
dc.subjectmethaneen
dc.subjectmethanolen
dc.subjecthydrogenen
dc.titleA facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysisen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalACS Applied Materials & Interfacesen
dc.eprint.versionPost-printen
dc.contributor.institutionDelft University of TechnologyFaculty of Applied Sciences, Chemical Engineering Building 58, Van der Maasweg 9 2629HZ, Delft, The Netherlandsen
kaust.authorBavykina, Anastasiya V.en
kaust.authorGascon, Jorgeen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.