Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

Handle URI:
http://hdl.handle.net/10754/625093
Title:
Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks
Authors:
Assi, Hala ( 0000-0002-3588-0680 ) ; Mouchaham, Georges ( 0000-0001-8696-9733 ) ; Steunou, Nathalie ( 0000-0002-7049-7388 ) ; Devic, Thomas; Serre, Christian
Abstract:
Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.
KAUST Department:
King Abdullah University of Science and Technology (KAUST)
Citation:
Assi H, Mouchaham G, Steunou N, Devic T, Serre C (2017) Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks. Chem Soc Rev 46: 3431–3452. Available: http://dx.doi.org/10.1039/c7cs00001d.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Soc. Rev.
Issue Date:
24-May-2017
DOI:
10.1039/c7cs00001d
Type:
Article
ISSN:
0306-0012; 1460-4744
Sponsors:
The authors acknowledge past and present coworkers involved in the synthesis and characterization of new MOFs, especially those involved in the chemistry of Ti-MOFs (H. Dan-Hardi, V. Guillerm, N. Guillou, P. Horcajada, T. L. A. Nguyen, F. Nouar, L. C. Pardo-Perez, F. Ragon and G. Férey).
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C7CS00001D#!divAbstract
Appears in Collections:
Articles

Full metadata record

DC FieldValue Language
dc.contributor.authorAssi, Halaen
dc.contributor.authorMouchaham, Georgesen
dc.contributor.authorSteunou, Nathalieen
dc.contributor.authorDevic, Thomasen
dc.contributor.authorSerre, Christianen
dc.date.accessioned2017-06-21T06:42:09Z-
dc.date.available2017-06-21T06:42:09Z-
dc.date.issued2017-05-24en
dc.identifier.citationAssi H, Mouchaham G, Steunou N, Devic T, Serre C (2017) Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks. Chem Soc Rev 46: 3431–3452. Available: http://dx.doi.org/10.1039/c7cs00001d.en
dc.identifier.issn0306-0012en
dc.identifier.issn1460-4744en
dc.identifier.doi10.1039/c7cs00001den
dc.identifier.urihttp://hdl.handle.net/10754/625093-
dc.description.abstractOwing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.en
dc.description.sponsorshipThe authors acknowledge past and present coworkers involved in the synthesis and characterization of new MOFs, especially those involved in the chemistry of Ti-MOFs (H. Dan-Hardi, V. Guillerm, N. Guillou, P. Horcajada, T. L. A. Nguyen, F. Nouar, L. C. Pardo-Perez, F. Ragon and G. Férey).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C7CS00001D#!divAbstracten
dc.titleTitanium coordination compounds: from discrete metal complexes to metal–organic frameworksen
dc.typeArticleen
dc.contributor.departmentKing Abdullah University of Science and Technology (KAUST)en
dc.identifier.journalChem. Soc. Rev.en
dc.contributor.institutionInstitut Lavoisier, UMR CNRS 8180, Université de Versailles St-Quentin en Yvelines, Université Paris Saclay, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, Franceen
dc.contributor.institutionInstitut des Matériaux Jean Rouxel (IMN), UMR 6502, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes Cedex 3, Franceen
dc.contributor.institutionInstitut des Matériaux Poreux de Paris, FRE 2000 CNRS Ecole Normale Supérieure, Ecole Supérieure de Physique et de Chimie Industrielles de Paris, PSL Research University, 75005 Paris, Franceen
kaust.authorMouchaham, Georgesen
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