Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration

Handle URI:
http://hdl.handle.net/10754/625006
Title:
Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration
Authors:
Cadiau, Amandine ( 0000-0002-3036-9197 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Adil, Karim ( 0000-0002-3804-1065 ) ; Bhatt, Prashant; Pillai, Renjith S. ( 0000-0003-0165-3305 ) ; Shkurenko, Aleksander ( 0000-0001-7136-2277 ) ; Martineau-Corcos, Charlotte ( 0000-0003-1887-1042 ) ; Maurin, Guillaume ( 0000-0002-2096-0450 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Natural gas must be dehydrated before it can be transported and used, but conventional drying agents such as activated alumina or inorganic molecular sieves require an energy-intensive desiccant-regeneration step. We report a hydrolytically stable fluorinated metal-organic framework, AlFFIVE-1-Ni (KAUST-8), with a periodic array of open metal coordination sites and fluorine moieties within the contracted square-shaped one-dimensional channel. This material selectively removed water vapor from gas streams containing CO2, N2, CH4, and higher hydrocarbons typical of natural gas, as well as selectively removed both H2O and CO2 in N2-containing streams. The complete desorption of the adsorbed water molecules contained by the AlFFIVE-1-Ni sorbent requires relatively moderate temperature (~105°C) and about half the energy input for commonly used desiccants.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Cadiau A, Belmabkhout Y, Adil K, Bhatt PM, Pillai RS, et al. (2017) Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration. Science 356: 731–735. Available: http://dx.doi.org/10.1126/science.aam8310.
Publisher:
American Association for the Advancement of Science (AAAS)
Journal:
Science
KAUST Grant Number:
CCF/1/1972-02-01; CCF/1/1972-8-01; OSR-2017-CPF-3325
Issue Date:
18-May-2017
DOI:
10.1126/science.aam8310
Type:
Article
ISSN:
0036-8075; 1095-9203
Sponsors:
Research reported in this publication was solely performed at KAUST and was supported by KAUST funds, KAUST funding grants (CCF/1/1972-02-01, CCF/1/1972-8-01, and OSR-2017-CPF-3325), and Aramco. The data reported in the paper are presented in the main text and the supplementary materials. Crystal structures of the as-synthesized AlFFIVE-1-Ni, the dehydrated AlFFIVE-1-Ni, AlFFIVE-1-Ni (rehydrated), AlFFIVE-1-Ni·1.48H2O·0.26CO2, and FeFFIVE-1-Ni are available free of charge from the Cambridge Crystallographic Data Centre (CCDC) under reference nos. CCDC 1538217, 1538215, 1538216, 1538219, and 1538218. A.C., Y.B., K.A., P.M.B., M.E., and KAUST have filed provisional patents (WO2016/162834A1 and WO2016/162835A1) pertaining to the results presented herein. K.A., M.E., and A.C. conceptualized the design and the construction of the reported MOF materials; A.C. carried out the materials synthesis; K.A., A.C., and A.S. conducted and interpreted the crystallographic experiments; P.M.B., Y.B., and A.C. conducted and interpreted low-pressure adsorption experiments; Y.B. and P.M.B. contributed to conceptualizing, designing, conducting, and interpreting calorimetric and mixed adsorption experiments; R.S.P. and G.M. performed andanalyzed the DFT calculations; C.M.-C. conducted and analyzed the solid-state NMR experiments; and K.A., Y.B., A.C., and M.E. wrote the manuscript.
Additional Links:
http://science.sciencemag.org/content/356/6339/731.full
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorCadiau, Amandineen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorAdil, Karimen
dc.contributor.authorBhatt, Prashanten
dc.contributor.authorPillai, Renjith S.en
dc.contributor.authorShkurenko, Aleksanderen
dc.contributor.authorMartineau-Corcos, Charlotteen
dc.contributor.authorMaurin, Guillaumeen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2017-06-14T12:17:33Z-
dc.date.available2017-06-14T12:17:33Z-
dc.date.issued2017-05-18en
dc.identifier.citationCadiau A, Belmabkhout Y, Adil K, Bhatt PM, Pillai RS, et al. (2017) Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration. Science 356: 731–735. Available: http://dx.doi.org/10.1126/science.aam8310.en
dc.identifier.issn0036-8075en
dc.identifier.issn1095-9203en
dc.identifier.doi10.1126/science.aam8310en
dc.identifier.urihttp://hdl.handle.net/10754/625006-
dc.description.abstractNatural gas must be dehydrated before it can be transported and used, but conventional drying agents such as activated alumina or inorganic molecular sieves require an energy-intensive desiccant-regeneration step. We report a hydrolytically stable fluorinated metal-organic framework, AlFFIVE-1-Ni (KAUST-8), with a periodic array of open metal coordination sites and fluorine moieties within the contracted square-shaped one-dimensional channel. This material selectively removed water vapor from gas streams containing CO2, N2, CH4, and higher hydrocarbons typical of natural gas, as well as selectively removed both H2O and CO2 in N2-containing streams. The complete desorption of the adsorbed water molecules contained by the AlFFIVE-1-Ni sorbent requires relatively moderate temperature (~105°C) and about half the energy input for commonly used desiccants.en
dc.description.sponsorshipResearch reported in this publication was solely performed at KAUST and was supported by KAUST funds, KAUST funding grants (CCF/1/1972-02-01, CCF/1/1972-8-01, and OSR-2017-CPF-3325), and Aramco. The data reported in the paper are presented in the main text and the supplementary materials. Crystal structures of the as-synthesized AlFFIVE-1-Ni, the dehydrated AlFFIVE-1-Ni, AlFFIVE-1-Ni (rehydrated), AlFFIVE-1-Ni·1.48H2O·0.26CO2, and FeFFIVE-1-Ni are available free of charge from the Cambridge Crystallographic Data Centre (CCDC) under reference nos. CCDC 1538217, 1538215, 1538216, 1538219, and 1538218. A.C., Y.B., K.A., P.M.B., M.E., and KAUST have filed provisional patents (WO2016/162834A1 and WO2016/162835A1) pertaining to the results presented herein. K.A., M.E., and A.C. conceptualized the design and the construction of the reported MOF materials; A.C. carried out the materials synthesis; K.A., A.C., and A.S. conducted and interpreted the crystallographic experiments; P.M.B., Y.B., and A.C. conducted and interpreted low-pressure adsorption experiments; Y.B. and P.M.B. contributed to conceptualizing, designing, conducting, and interpreting calorimetric and mixed adsorption experiments; R.S.P. and G.M. performed andanalyzed the DFT calculations; C.M.-C. conducted and analyzed the solid-state NMR experiments; and K.A., Y.B., A.C., and M.E. wrote the manuscript.en
dc.publisherAmerican Association for the Advancement of Science (AAAS)en
dc.relation.urlhttp://science.sciencemag.org/content/356/6339/731.fullen
dc.titleHydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydrationen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalScienceen
dc.contributor.institutionInstitut Lavoisier de Versailles (ILV), UMR CNRS 8180, Université de Versailles St–Quentin en Yvelines (UVSQ), 45 Avenue des Etats-Unis, 78035 Versailles Cedex, Franceen
dc.contributor.institutionCEMHTI-CNRS, UPR 3079, 1D Avenue de la Recherche Scientifique, 45071 Orléans Cedex 2, Franceen
dc.contributor.institutionInstitut Charles Gerhardt Montpellier (UMR CNRS 5253), Université Montpellier, Place Eugène Bataillon, 34095 Montpellier Cedex 05, Franceen
kaust.authorCadiau, Amandineen
kaust.authorBelmabkhout, Youssefen
kaust.authorAdil, Karimen
kaust.authorBhatt, Prashanten
kaust.authorPillai, Renjith S.en
kaust.authorShkurenko, Aleksanderen
kaust.authorEddaoudi, Mohameden
kaust.grant.numberCCF/1/1972-02-01en
kaust.grant.numberCCF/1/1972-8-01en
kaust.grant.numberOSR-2017-CPF-3325en
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