Selective Catalytic Hydrogenation of Arenols by a Well-Defined Complex of Ruthenium and Phosphorus–Nitrogen PN3–Pincer Ligand Containing a Phenanthroline Backbone

Handle URI:
http://hdl.handle.net/10754/624970
Title:
Selective Catalytic Hydrogenation of Arenols by a Well-Defined Complex of Ruthenium and Phosphorus–Nitrogen PN3–Pincer Ligand Containing a Phenanthroline Backbone
Authors:
Li, Huaifeng ( 0000-0001-9661-803X ) ; Wang, Yuan; Lai, Zhiping ( 0000-0001-9555-6009 ) ; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Selective catalytic hydrogenation of aromatic compounds is extremely challenging using transition-metal catalysts. Hydrogenation of arenols to substituted tetrahydronaphthols or cyclohexanols has been reported only with heterogeneous catalysts. Herein, we demonstrate the selective hydrogenation of arenols to the corresponding tetrahydronaphthols or cyclohexanols catalyzed by a phenanthroline-based PN3-ruthenium pincer catalyst.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC); Advanced Membranes and Porous Materials Research Center
Citation:
Li H, Wang Y, Lai Z, Huang K-W (2017) Selective Catalytic Hydrogenation of Arenols by a Well-Defined Complex of Ruthenium and Phosphorus–Nitrogen PN3–Pincer Ligand Containing a Phenanthroline Backbone. ACS Catalysis: 4446–4450. Available: http://dx.doi.org/10.1021/acscatal.7b01316.
Publisher:
American Chemical Society (ACS)
Journal:
ACS Catalysis
Issue Date:
30-May-2017
DOI:
10.1021/acscatal.7b01316
Type:
Article
ISSN:
2155-5435; 2155-5435
Sponsors:
Financial support was provided by King Abdullah University of Science and Technology (KAUST).
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/acscatal.7b01316
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLi, Huaifengen
dc.contributor.authorWang, Yuanen
dc.contributor.authorLai, Zhipingen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2017-06-13T05:51:05Z-
dc.date.available2017-06-13T05:51:05Z-
dc.date.issued2017-05-30en
dc.identifier.citationLi H, Wang Y, Lai Z, Huang K-W (2017) Selective Catalytic Hydrogenation of Arenols by a Well-Defined Complex of Ruthenium and Phosphorus–Nitrogen PN3–Pincer Ligand Containing a Phenanthroline Backbone. ACS Catalysis: 4446–4450. Available: http://dx.doi.org/10.1021/acscatal.7b01316.en
dc.identifier.issn2155-5435en
dc.identifier.issn2155-5435en
dc.identifier.doi10.1021/acscatal.7b01316en
dc.identifier.urihttp://hdl.handle.net/10754/624970-
dc.description.abstractSelective catalytic hydrogenation of aromatic compounds is extremely challenging using transition-metal catalysts. Hydrogenation of arenols to substituted tetrahydronaphthols or cyclohexanols has been reported only with heterogeneous catalysts. Herein, we demonstrate the selective hydrogenation of arenols to the corresponding tetrahydronaphthols or cyclohexanols catalyzed by a phenanthroline-based PN3-ruthenium pincer catalyst.en
dc.description.sponsorshipFinancial support was provided by King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/acscatal.7b01316en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acscatal.7b01316.en
dc.subjectarenolsen
dc.subjectcatalysisen
dc.subjecthydrogenationen
dc.subjectphenanthroline backboneen
dc.subjectPN3-pinceren
dc.titleSelective Catalytic Hydrogenation of Arenols by a Well-Defined Complex of Ruthenium and Phosphorus–Nitrogen PN3–Pincer Ligand Containing a Phenanthroline Backboneen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.identifier.journalACS Catalysisen
dc.eprint.versionPost-printen
kaust.authorLi, Huaifengen
kaust.authorWang, Yuanen
kaust.authorLai, Zhipingen
kaust.authorHuang, Kuo-Weien
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