Sequential Dip-spin Coating Method: Fully Infiltration of MAPbI 3-x Cl x into Mesoporous TiO 2 for Stable Hybrid Perovskite Solar Cells

Handle URI:
http://hdl.handle.net/10754/624045
Title:
Sequential Dip-spin Coating Method: Fully Infiltration of MAPbI 3-x Cl x into Mesoporous TiO 2 for Stable Hybrid Perovskite Solar Cells
Authors:
Kim, Woochul; Park, Jiyoon; Kim, Hyeonghun; Pak, Yusin; Lee, Heon; Jung, Gun Young
Abstract:
Organic-inorganic hybrid perovskite solar cells (PSCs) have reached a power conversion efficiency of 22.1% in a short period (∼7 years), which has been obtainable in silicon-based solar cells for decades. The high power conversion efficiency and simple fabrication process render perovskite solar cells as potential future power generators, after overcoming the lack of long-term stability, for which the deposition of void-free and pore-filled perovskite films on mesoporous TiO2 layers is the key pursuit. In this research, we developed a sequential dip-spin coating method in which the perovskite solution can easily infiltrate the pores within the TiO2 nanoparticulate layer, and the resultant film has large crystalline grains without voids between them. As a result, a higher short circuit current is achieved owing to the large interfacial area of TiO2/perovskite, along with enhanced power conversion efficiency, compared to the conventional spin coating method. The as-made pore-filled and void-free perovskite film avoids intrinsic moisture and air and can effectively protect the diffusion of degradation factors into the perovskite film, which is advantageous for the long-term stability of PSCs.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Citation:
Kim W, Park J, Kim H, Pak Y, Lee H, et al. (2017) Sequential Dip-spin Coating Method: Fully Infiltration of MAPbI 3-x Cl x into Mesoporous TiO 2 for Stable Hybrid Perovskite Solar Cells. Electrochimica Acta. Available: http://dx.doi.org/10.1016/j.electacta.2017.05.184.
Publisher:
Elsevier BV
Journal:
Electrochimica Acta
Issue Date:
31-May-2017
DOI:
10.1016/j.electacta.2017.05.184
Type:
Article
ISSN:
0013-4686
Sponsors:
This work was supported by the Pioneer Research Center Program (NRF-2016M3C1A3908893) and by the Basic Science Research Program (NRF-2016R1A2B4006395) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. The research was partially supported by the GIST Research Institute (GRI) project through a grant provided by GIST in 2017.
Additional Links:
http://www.sciencedirect.com/science/article/pii/S0013468617312185
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorKim, Woochulen
dc.contributor.authorPark, Jiyoonen
dc.contributor.authorKim, Hyeonghunen
dc.contributor.authorPak, Yusinen
dc.contributor.authorLee, Heonen
dc.contributor.authorJung, Gun Youngen
dc.date.accessioned2017-06-05T06:02:25Z-
dc.date.available2017-06-05T06:02:25Z-
dc.date.issued2017-05-31en
dc.identifier.citationKim W, Park J, Kim H, Pak Y, Lee H, et al. (2017) Sequential Dip-spin Coating Method: Fully Infiltration of MAPbI 3-x Cl x into Mesoporous TiO 2 for Stable Hybrid Perovskite Solar Cells. Electrochimica Acta. Available: http://dx.doi.org/10.1016/j.electacta.2017.05.184.en
dc.identifier.issn0013-4686en
dc.identifier.doi10.1016/j.electacta.2017.05.184en
dc.identifier.urihttp://hdl.handle.net/10754/624045-
dc.description.abstractOrganic-inorganic hybrid perovskite solar cells (PSCs) have reached a power conversion efficiency of 22.1% in a short period (∼7 years), which has been obtainable in silicon-based solar cells for decades. The high power conversion efficiency and simple fabrication process render perovskite solar cells as potential future power generators, after overcoming the lack of long-term stability, for which the deposition of void-free and pore-filled perovskite films on mesoporous TiO2 layers is the key pursuit. In this research, we developed a sequential dip-spin coating method in which the perovskite solution can easily infiltrate the pores within the TiO2 nanoparticulate layer, and the resultant film has large crystalline grains without voids between them. As a result, a higher short circuit current is achieved owing to the large interfacial area of TiO2/perovskite, along with enhanced power conversion efficiency, compared to the conventional spin coating method. The as-made pore-filled and void-free perovskite film avoids intrinsic moisture and air and can effectively protect the diffusion of degradation factors into the perovskite film, which is advantageous for the long-term stability of PSCs.en
dc.description.sponsorshipThis work was supported by the Pioneer Research Center Program (NRF-2016M3C1A3908893) and by the Basic Science Research Program (NRF-2016R1A2B4006395) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. The research was partially supported by the GIST Research Institute (GRI) project through a grant provided by GIST in 2017.en
dc.publisherElsevier BVen
dc.relation.urlhttp://www.sciencedirect.com/science/article/pii/S0013468617312185en
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Electrochimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Electrochimica Acta, [, , (2017-05-31)] DOI: 10.1016/j.electacta.2017.05.184 . © 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectPerovskite solar cellen
dc.subjectMesoporous TiO2en
dc.subjectDippingen
dc.subjectHybrid perovskiteen
dc.subjectStabilityen
dc.titleSequential Dip-spin Coating Method: Fully Infiltration of MAPbI 3-x Cl x into Mesoporous TiO 2 for Stable Hybrid Perovskite Solar Cellsen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalElectrochimica Actaen
dc.eprint.versionPost-printen
dc.contributor.institutionSchool of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 61005, Republic of Koreaen
dc.contributor.institutionDepartment of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Koreaen
kaust.authorPak, Yusinen
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