Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net

Handle URI:
http://hdl.handle.net/10754/623794
Title:
Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net
Authors:
Chen, Zhijie; Weselinski, Lukasz Jan ( 0000-0003-4516-2727 ) ; Adil, Karim ( 0000-0002-3804-1065 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Shkurenko, Aleksander ( 0000-0001-7136-2277 ) ; Jiang, Hao; Bhatt, Prashant; Guillerm, Vincent ( 0000-0003-3460-223X ) ; Dauzon, Emilie; Xue, Dongxu; O’Keeffe, Michael; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Highly connected and edge-transitive nets are of prime importance in crystal chemistry and are regarded as ideal blueprints for the rational design and construction of metal-organic frameworks (MOFs). We report the design and synthesis of highly connected MOFs based on reticulation of the sole two edge-transitive nets with a vertex figure as double six-membered-ring (d6R) building unit, namely the (4,12)-coordinated shp net (square and hexagonal-prism) and the (6,12)-coordinated alb net (aluminum diboride, hexagonal-prism and trigonal-prism). Decidedly, the combination of our recently isolated 12-connected (12-c) rare-earth (RE) nonanuclear [RE(μ-OH)(μ-O)(OC-)] carboxylate-based cluster, points of extension matching the 12 vertices of hexagonal-prism d6R, with 4-connected (4-c) square porphyrinic tetracarboxylate ligand led to the formation of the targeted RE-shp-MOF. This is the first time that RE-MOFs based on 12-c molecular building blocks (MBBs), d6R building units, have been deliberately targeted and successfully isolated, paving the way for the long-awaited (6,12)-c MOF with alb topology. Indeed, combination of a custom-designed hexacarboxylate ligand with RE salts led to the formation of the first related alb-MOF, RE-alb-MOF. Intuitively, we successfully transplanted the alb topology to another chemical system and constructed the first indium-based alb-MOF, In-alb-MOF, by employing trinuclear [In(μ-O)(OC-)] as the requisite 6-connected trigonal-prism and purposely made a dodecacarboxylate ligand as a compatible 12-c MBB. Prominently, the dodecacarboxylate ligand was employed to transplant shp topology into copper-based MOFs by employing the copper paddlewheel [Cu(OC-)] as the complementary square building unit, affording the first Cu-shp-MOF. We revealed that highly connected edge-transitive nets such shp and alb are ideal for topological transplantation and deliberate construction of related MOFs based on minimal edge-transitive nets.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Chen Z, Weseliński ŁJ, Adil K, Belmabkhout Y, Shkurenko A, et al. (2017) Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net. Journal of the American Chemical Society 139: 3265–3274. Available: http://dx.doi.org/10.1021/jacs.7b00219.
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
5-Feb-2017
DOI:
10.1021/jacs.7b00219
Type:
Article
ISSN:
0002-7863; 1520-5126
Sponsors:
Research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
Additional Links:
http://pubs.acs.org/doi/abs/10.1021/jacs.7b00219
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Zhijieen
dc.contributor.authorWeselinski, Lukasz Janen
dc.contributor.authorAdil, Karimen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorShkurenko, Aleksanderen
dc.contributor.authorJiang, Haoen
dc.contributor.authorBhatt, Prashanten
dc.contributor.authorGuillerm, Vincenten
dc.contributor.authorDauzon, Emilieen
dc.contributor.authorXue, Dongxuen
dc.contributor.authorO’Keeffe, Michaelen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2017-05-31T11:23:05Z-
dc.date.available2017-05-31T11:23:05Z-
dc.date.issued2017-02-05en
dc.identifier.citationChen Z, Weseliński ŁJ, Adil K, Belmabkhout Y, Shkurenko A, et al. (2017) Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net. Journal of the American Chemical Society 139: 3265–3274. Available: http://dx.doi.org/10.1021/jacs.7b00219.en
dc.identifier.issn0002-7863en
dc.identifier.issn1520-5126en
dc.identifier.doi10.1021/jacs.7b00219en
dc.identifier.urihttp://hdl.handle.net/10754/623794-
dc.description.abstractHighly connected and edge-transitive nets are of prime importance in crystal chemistry and are regarded as ideal blueprints for the rational design and construction of metal-organic frameworks (MOFs). We report the design and synthesis of highly connected MOFs based on reticulation of the sole two edge-transitive nets with a vertex figure as double six-membered-ring (d6R) building unit, namely the (4,12)-coordinated shp net (square and hexagonal-prism) and the (6,12)-coordinated alb net (aluminum diboride, hexagonal-prism and trigonal-prism). Decidedly, the combination of our recently isolated 12-connected (12-c) rare-earth (RE) nonanuclear [RE(μ-OH)(μ-O)(OC-)] carboxylate-based cluster, points of extension matching the 12 vertices of hexagonal-prism d6R, with 4-connected (4-c) square porphyrinic tetracarboxylate ligand led to the formation of the targeted RE-shp-MOF. This is the first time that RE-MOFs based on 12-c molecular building blocks (MBBs), d6R building units, have been deliberately targeted and successfully isolated, paving the way for the long-awaited (6,12)-c MOF with alb topology. Indeed, combination of a custom-designed hexacarboxylate ligand with RE salts led to the formation of the first related alb-MOF, RE-alb-MOF. Intuitively, we successfully transplanted the alb topology to another chemical system and constructed the first indium-based alb-MOF, In-alb-MOF, by employing trinuclear [In(μ-O)(OC-)] as the requisite 6-connected trigonal-prism and purposely made a dodecacarboxylate ligand as a compatible 12-c MBB. Prominently, the dodecacarboxylate ligand was employed to transplant shp topology into copper-based MOFs by employing the copper paddlewheel [Cu(OC-)] as the complementary square building unit, affording the first Cu-shp-MOF. We revealed that highly connected edge-transitive nets such shp and alb are ideal for topological transplantation and deliberate construction of related MOFs based on minimal edge-transitive nets.en
dc.description.sponsorshipResearch reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/jacs.7b00219en
dc.titleApplying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Neten
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionSchool of Molecular Sciences, Arizona State University, Tempe, AZ, 85287, , United Statesen
kaust.authorChen, Zhijieen
kaust.authorWeselinski, Lukasz Janen
kaust.authorAdil, Karimen
kaust.authorBelmabkhout, Youssefen
kaust.authorShkurenko, Aleksanderen
kaust.authorJiang, Haoen
kaust.authorBhatt, Prashanten
kaust.authorGuillerm, Vincenten
kaust.authorDauzon, Emilieen
kaust.authorXue, Dongxuen
kaust.authorEddaoudi, Mohameden
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