A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester

Handle URI:
http://hdl.handle.net/10754/623779
Title:
A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester
Authors:
Samal, Akshaya Kumar ( 0000-0002-7623-3711 ) ; Zhu, Haibo; Harb, Moussab ( 0000-0001-5540-9792 ) ; Sangaru, Shiv ( 0000-0002-3506-8238 ) ; Anjum, Dalaver H.; Hedhili, Mohamed N. ( 0000-0002-3624-036X ) ; Saih, Youssef; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.
KAUST Department:
KAUST Catalysis Center (KCC); Imaging and Characterization Core Lab
Citation:
Samal AK, Zhu H, Harb M, Sangaru SS, Anjum DH, et al. (2017) A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester. Catal Sci Technol 7: 581–586. Available: http://dx.doi.org/10.1039/c6cy02187e.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Catal. Sci. Technol.
Issue Date:
24-Nov-2016
DOI:
10.1039/c6cy02187e
Type:
Article
ISSN:
2044-4753; 2044-4761
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/CY/C6CY02187E#!divAbstract
Appears in Collections:
Articles; Advanced Nanofabrication, Imaging and Characterization Core Lab; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorSamal, Akshaya Kumaren
dc.contributor.authorZhu, Haiboen
dc.contributor.authorHarb, Moussaben
dc.contributor.authorSangaru, Shiven
dc.contributor.authorAnjum, Dalaver H.en
dc.contributor.authorHedhili, Mohamed N.en
dc.contributor.authorSaih, Youssefen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2017-05-31T11:23:04Z-
dc.date.available2017-05-31T11:23:04Z-
dc.date.issued2016-11-24en
dc.identifier.citationSamal AK, Zhu H, Harb M, Sangaru SS, Anjum DH, et al. (2017) A general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of ester. Catal Sci Technol 7: 581–586. Available: http://dx.doi.org/10.1039/c6cy02187e.en
dc.identifier.issn2044-4753en
dc.identifier.issn2044-4761en
dc.identifier.doi10.1039/c6cy02187een
dc.identifier.urihttp://hdl.handle.net/10754/623779-
dc.description.abstractA versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C2H5)(3)H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/CY/C6CY02187E#!divAbstracten
dc.titleA general approach for the synthesis of bimetallic M–Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of esteren
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentImaging and Characterization Core Laben
dc.identifier.journalCatal. Sci. Technol.en
kaust.authorSamal, Akshaya Kumaren
kaust.authorZhu, Haiboen
kaust.authorHarb, Moussaben
kaust.authorSangaru, Shiven
kaust.authorAnjum, Dalaver H.en
kaust.authorHedhili, Mohamed N.en
kaust.authorSaih, Youssefen
kaust.authorBasset, Jean-Marieen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.