Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species

Handle URI:
http://hdl.handle.net/10754/623602
Title:
Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species
Authors:
Santoro, Orlando; Nahra, Fady; Cordes, David B.; Slawin, Alexandra M.Z.; Nolan, Steven P.; Cazin, Catherine S.J. ( 0000-0002-9094-8131 )
Abstract:
The synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.
Citation:
Santoro O, Nahra F, Cordes DB, Slawin AMZ, Nolan SP, et al. (2016) Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY 2 ] (NHC = N -Heterocyclic carbene, X, Y = Cl, Br) species. Journal of Molecular Catalysis A: Chemical 423: 85–91. Available: http://dx.doi.org/10.1016/j.molcata.2016.05.031.
Publisher:
Elsevier BV
Journal:
Journal of Molecular Catalysis A: Chemical
KAUST Grant Number:
OSR-2015-CCF-1974-03
Issue Date:
4-Jun-2016
DOI:
10.1016/j.molcata.2016.05.031
Type:
Article
ISSN:
1381-1169
Sponsors:
The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.
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Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorSantoro, Orlandoen
dc.contributor.authorNahra, Fadyen
dc.contributor.authorCordes, David B.en
dc.contributor.authorSlawin, Alexandra M.Z.en
dc.contributor.authorNolan, Steven P.en
dc.contributor.authorCazin, Catherine S.J.en
dc.date.accessioned2017-05-15T10:35:10Z-
dc.date.available2017-05-15T10:35:10Z-
dc.date.issued2016-06-04en
dc.identifier.citationSantoro O, Nahra F, Cordes DB, Slawin AMZ, Nolan SP, et al. (2016) Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY 2 ] (NHC = N -Heterocyclic carbene, X, Y = Cl, Br) species. Journal of Molecular Catalysis A: Chemical 423: 85–91. Available: http://dx.doi.org/10.1016/j.molcata.2016.05.031.en
dc.identifier.issn1381-1169en
dc.identifier.doi10.1016/j.molcata.2016.05.031en
dc.identifier.urihttp://hdl.handle.net/10754/623602-
dc.description.abstractThe synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.en
dc.description.sponsorshipThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.en
dc.publisherElsevier BVen
dc.subjectN-Heterocyclic carbenesen
dc.subjectZincen
dc.subjectMethylationen
dc.subjectCO2en
dc.titleSynthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) speciesen
dc.typeArticleen
dc.identifier.journalJournal of Molecular Catalysis A: Chemicalen
dc.contributor.institutionEaStCHEM School of Chemistry, University of St. Andrews, St Andrews KY16 9ST, UKen
dc.contributor.institutionUniversiteit Gent, Department of Inorganic and Physical Chemistry, Krijgslaan 281, S-3, B-9000 Ghent, Belgiumen
dc.contributor.institutionKing Saud University, Department of Chemistry, College of Sciences, P.O. Box 2455, Riyadh 11451, Saudi Arabiaen
kaust.grant.numberOSR-2015-CCF-1974-03en
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