Molecular active plasmonics: controlling plasmon resonances with molecular machines

Handle URI:
http://hdl.handle.net/10754/623565
Title:
Molecular active plasmonics: controlling plasmon resonances with molecular machines
Authors:
Zheng, Yue Bing; Yang, Ying-Wei; Jensen, Lasse; Fang, Lei; Juluri, Bala Krishna; Flood, Amar H.; Weiss, Paul S.; Stoddart, J. Fraser; Huang, Tony Jun
Abstract:
The paper studies the molecular-level active control of localized surface plasmon resonances (LSPRs) of Au nanodisk arrays with molecular machines. Two types of molecular machines - azobenzene and rotaxane - have been demonstrated to enable the reversible tuning of the LSPRs via the controlled mechanical movements. Azobenzene molecules have the property of trans-cis photoisomerization and enable the photo-induced nematic (N)-isotropic (I) phase transition of the liquid crystals (LCs) that contain the molecules as dopant. The phase transition of the azobenzene-doped LCs causes the refractive-index difference of the LCs, resulting in the reversible peak shift of the LSPRs of the embedded Au nanodisks due to the sensitivity of the LSPRs to the disks' surroundings' refractive index. Au nanodisk array, coated with rotaxanes, switches its LSPRs reversibly when it is exposed to chemical oxidants and reductants alternatively. The correlation between the peak shift of the LSPRs and the chemically driven mechanical movement of rotaxanes is supported by control experiments and a time-dependent density functional theory (TDDFT)-based, microscopic model.
Citation:
Zheng YB, Yang Y-W, Jensen L, Fang L, Juluri BK, et al. (2009) Molecular active plasmonics: controlling plasmon resonances with molecular machines. Plasmonics: Nanoimaging, Nanofabrication, and their Applications V. Available: http://dx.doi.org/10.1117/12.824525.
Publisher:
SPIE-Intl Soc Optical Eng
Journal:
Plasmonics: Nanoimaging, Nanofabrication, and their Applications V
Conference/Event name:
Plasmonics: Nanoimaging, Nanofabrication, and their Applications V
Issue Date:
26-Aug-2009
DOI:
10.1117/12.824525
Type:
Conference Paper
Sponsors:
We thank Dr. Vincent Hsiao for his contribution to the experimental part of the azobenzene-based active tuning of the localized surface plasmon resonances, Dr. Amanda J. Haes for the MATHCAD code used in the Kramers−Kronig analysis, and Dr. Vincent Crespi for helpful discussions. This research was supported by the Air Force Office of Scientific Research (AFOSR), the National Science Foundation (NSF), and the Penn State Center for Nanoscale Science (an NSF-funded MRSEC). Components of this work were conducted at the Pennsylvania State University node of the NSF-funded National Nanotechnology Infrastructure Network. One of the authors (Y.B.Z.) thanks the support of a KAUST Scholar Award and the Founder’s Prize and Grant of the American Academy of Mechanics.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorZheng, Yue Bingen
dc.contributor.authorYang, Ying-Weien
dc.contributor.authorJensen, Lasseen
dc.contributor.authorFang, Leien
dc.contributor.authorJuluri, Bala Krishnaen
dc.contributor.authorFlood, Amar H.en
dc.contributor.authorWeiss, Paul S.en
dc.contributor.authorStoddart, J. Fraseren
dc.contributor.authorHuang, Tony Junen
dc.date.accessioned2017-05-15T10:35:08Z-
dc.date.available2017-05-15T10:35:08Z-
dc.date.issued2009-08-26en
dc.identifier.citationZheng YB, Yang Y-W, Jensen L, Fang L, Juluri BK, et al. (2009) Molecular active plasmonics: controlling plasmon resonances with molecular machines. Plasmonics: Nanoimaging, Nanofabrication, and their Applications V. Available: http://dx.doi.org/10.1117/12.824525.en
dc.identifier.doi10.1117/12.824525en
dc.identifier.urihttp://hdl.handle.net/10754/623565-
dc.description.abstractThe paper studies the molecular-level active control of localized surface plasmon resonances (LSPRs) of Au nanodisk arrays with molecular machines. Two types of molecular machines - azobenzene and rotaxane - have been demonstrated to enable the reversible tuning of the LSPRs via the controlled mechanical movements. Azobenzene molecules have the property of trans-cis photoisomerization and enable the photo-induced nematic (N)-isotropic (I) phase transition of the liquid crystals (LCs) that contain the molecules as dopant. The phase transition of the azobenzene-doped LCs causes the refractive-index difference of the LCs, resulting in the reversible peak shift of the LSPRs of the embedded Au nanodisks due to the sensitivity of the LSPRs to the disks' surroundings' refractive index. Au nanodisk array, coated with rotaxanes, switches its LSPRs reversibly when it is exposed to chemical oxidants and reductants alternatively. The correlation between the peak shift of the LSPRs and the chemically driven mechanical movement of rotaxanes is supported by control experiments and a time-dependent density functional theory (TDDFT)-based, microscopic model.en
dc.description.sponsorshipWe thank Dr. Vincent Hsiao for his contribution to the experimental part of the azobenzene-based active tuning of the localized surface plasmon resonances, Dr. Amanda J. Haes for the MATHCAD code used in the Kramers−Kronig analysis, and Dr. Vincent Crespi for helpful discussions. This research was supported by the Air Force Office of Scientific Research (AFOSR), the National Science Foundation (NSF), and the Penn State Center for Nanoscale Science (an NSF-funded MRSEC). Components of this work were conducted at the Pennsylvania State University node of the NSF-funded National Nanotechnology Infrastructure Network. One of the authors (Y.B.Z.) thanks the support of a KAUST Scholar Award and the Founder’s Prize and Grant of the American Academy of Mechanics.en
dc.publisherSPIE-Intl Soc Optical Engen
dc.subjectplasmonicsen
dc.subjectmolecular plasmonicsen
dc.subjectmolecular active plasmonicsen
dc.subjectmolecular machinesen
dc.subjectrotaxanesen
dc.subjectazobenzenesen
dc.subjectlocalized surface plasmon resonancesen
dc.subjectAu nanodisksen
dc.subjectliquid crystalsen
dc.subjecttime-dependent density functional theoryen
dc.titleMolecular active plasmonics: controlling plasmon resonances with molecular machinesen
dc.typeConference Paperen
dc.identifier.journalPlasmonics: Nanoimaging, Nanofabrication, and their Applications Ven
dc.conference.date2009-08-02 to 2009-08-06en
dc.conference.namePlasmonics: Nanoimaging, Nanofabrication, and their Applications Ven
dc.conference.locationSan Diego, CA, USAen
dc.contributor.institutionThe Pennsylvania State University, University Park, Pennsylvania, USA 16802en
dc.contributor.institutionNorthwestern University, Evanston, Illinois, USA 60208en
dc.contributor.institutionIndiana University, Bloomington, Indiana, USA 47405en
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.