Mesoporous Bragg reflectors: block-copolymer self-assembly leads to building blocks with well defined continuous pores and high control over optical properties

Handle URI:
http://hdl.handle.net/10754/623563
Title:
Mesoporous Bragg reflectors: block-copolymer self-assembly leads to building blocks with well defined continuous pores and high control over optical properties
Authors:
Guldin, S.; Kolle, M.; Stefik, M.; Wiesner, U.; Steiner, U.
Abstract:
Mesoporous distributed Bragg re ectors (MDBRs) exhibit porosity on the sub-optical length scale. This makes them ideally suited as sensing platforms in biology and chemistry as well as for light management in optoelectronic devices. Here we present a new fast forward route for the fabrication of MDBRs which relies on the self-assembling properties of the block copolymer poly(isoprene-block -ethylene oxide) (PI-b -PEO) in combination with sol-gel chemistry. The interplay between structure directing organic host and co-assembled inorganic guest allows the ne tuning of refractive index in the outcome material. The refractive index dierence between the high and low porosity layer can be as high as 0.4, with the optical interfaces being well dened. Following a 30 min annealing protocol after each layer deposition enables the fast and reliable stacking of MDBRs which exhibit a continuous TiO2 network with large accessible pores and high optical quality.
Citation:
Guldin S, Kolle M, Stefik M, Wiesner U, Steiner U (2011) Mesoporous Bragg reflectors: block-copolymer self-assembly leads to building blocks with well defined continuous pores and high control over optical properties. Active Photonic Materials IV. Available: http://dx.doi.org/10.1117/12.893818.
Publisher:
SPIE-Intl Soc Optical Eng
Journal:
Active Photonic Materials IV
KAUST Grant Number:
KUS-C1-018-02
Conference/Event name:
Active Photonic Materials IV
Issue Date:
19-Aug-2011
DOI:
10.1117/12.893818
Type:
Conference Paper
Sponsors:
This publication is based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), the EPSRC (EP/F056702/1 and EP/F065884/1), the Department of Energy (DE-FG02 87ER45298) through the Cornell Fuel Cell Institute (CFCI) and the National Science Foundation (DMR-0605856). M.S. was supported by the Cornell Fuel Cell Institute and the Energy Materials Center at Cornell (EMC2), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001086.
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Full metadata record

DC FieldValue Language
dc.contributor.authorGuldin, S.en
dc.contributor.authorKolle, M.en
dc.contributor.authorStefik, M.en
dc.contributor.authorWiesner, U.en
dc.contributor.authorSteiner, U.en
dc.date.accessioned2017-05-15T10:35:08Z-
dc.date.available2017-05-15T10:35:08Z-
dc.date.issued2011-08-19en
dc.identifier.citationGuldin S, Kolle M, Stefik M, Wiesner U, Steiner U (2011) Mesoporous Bragg reflectors: block-copolymer self-assembly leads to building blocks with well defined continuous pores and high control over optical properties. Active Photonic Materials IV. Available: http://dx.doi.org/10.1117/12.893818.en
dc.identifier.doi10.1117/12.893818en
dc.identifier.urihttp://hdl.handle.net/10754/623563-
dc.description.abstractMesoporous distributed Bragg re ectors (MDBRs) exhibit porosity on the sub-optical length scale. This makes them ideally suited as sensing platforms in biology and chemistry as well as for light management in optoelectronic devices. Here we present a new fast forward route for the fabrication of MDBRs which relies on the self-assembling properties of the block copolymer poly(isoprene-block -ethylene oxide) (PI-b -PEO) in combination with sol-gel chemistry. The interplay between structure directing organic host and co-assembled inorganic guest allows the ne tuning of refractive index in the outcome material. The refractive index dierence between the high and low porosity layer can be as high as 0.4, with the optical interfaces being well dened. Following a 30 min annealing protocol after each layer deposition enables the fast and reliable stacking of MDBRs which exhibit a continuous TiO2 network with large accessible pores and high optical quality.en
dc.description.sponsorshipThis publication is based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), the EPSRC (EP/F056702/1 and EP/F065884/1), the Department of Energy (DE-FG02 87ER45298) through the Cornell Fuel Cell Institute (CFCI) and the National Science Foundation (DMR-0605856). M.S. was supported by the Cornell Fuel Cell Institute and the Energy Materials Center at Cornell (EMC2), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001086.en
dc.publisherSPIE-Intl Soc Optical Engen
dc.subjectBragg reectoren
dc.subjectphotonic crystalen
dc.subjectpolymeren
dc.subjectporosityen
dc.subjectself-assemblyen
dc.subjectTiO 2en
dc.titleMesoporous Bragg reflectors: block-copolymer self-assembly leads to building blocks with well defined continuous pores and high control over optical propertiesen
dc.typeConference Paperen
dc.identifier.journalActive Photonic Materials IVen
dc.conference.date2011-10-22 to 2011-10-25en
dc.conference.nameActive Photonic Materials IVen
dc.conference.locationSan Diego, CA, USAen
dc.contributor.institutionUniv. of Cambridge (United Kingdom)en
dc.contributor.institutionHarvard Univ. (USA)en
dc.contributor.institutionCornell Univ. (USA)en
dc.contributor.institutionEcole Polytechnique Fédérale de Lausanne (Switzerland)en
kaust.grant.numberKUS-C1-018-02en
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