Handle URI:
http://hdl.handle.net/10754/623551
Title:
Gold- N -Heterocyclic Carbene Complexes of Mineral Acids
Authors:
Brill, Marcel; Nahra, Fady; Gómez-Herrera, Alberto; Zinser, Caroline; Cordes, David B.; Slawin, Alexandra M. Z.; Nolan, Steven P. ( 0000-0001-9024-2035 )
Abstract:
We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer–Schuster rearrangement. They proved to be highly efficient in both reactions.
Citation:
Brill M, Nahra F, Gómez-Herrera A, Zinser C, Cordes DB, et al. (2016) Gold- N -Heterocyclic Carbene Complexes of Mineral Acids. ChemCatChem 9: 117–120. Available: http://dx.doi.org/10.1002/cctc.201601290.
Publisher:
Wiley-Blackwell
Journal:
ChemCatChem
KAUST Grant Number:
OSR-2015-CCF-1974-03
Issue Date:
8-Nov-2016
DOI:
10.1002/cctc.201601290
Type:
Article
ISSN:
1867-3880
Sponsors:
The authors gratefully acknowledge King Saud University for funding. This publication is based upon work partly supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.
Appears in Collections:
Publications Acknowledging KAUST Support

Full metadata record

DC FieldValue Language
dc.contributor.authorBrill, Marcelen
dc.contributor.authorNahra, Fadyen
dc.contributor.authorGómez-Herrera, Albertoen
dc.contributor.authorZinser, Carolineen
dc.contributor.authorCordes, David B.en
dc.contributor.authorSlawin, Alexandra M. Z.en
dc.contributor.authorNolan, Steven P.en
dc.date.accessioned2017-05-15T10:35:08Z-
dc.date.available2017-05-15T10:35:08Z-
dc.date.issued2016-11-08en
dc.identifier.citationBrill M, Nahra F, Gómez-Herrera A, Zinser C, Cordes DB, et al. (2016) Gold- N -Heterocyclic Carbene Complexes of Mineral Acids. ChemCatChem 9: 117–120. Available: http://dx.doi.org/10.1002/cctc.201601290.en
dc.identifier.issn1867-3880en
dc.identifier.doi10.1002/cctc.201601290en
dc.identifier.urihttp://hdl.handle.net/10754/623551-
dc.description.abstractWe have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer–Schuster rearrangement. They proved to be highly efficient in both reactions.en
dc.description.sponsorshipThe authors gratefully acknowledge King Saud University for funding. This publication is based upon work partly supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.en
dc.publisherWiley-Blackwellen
dc.subjectcatalysisen
dc.subjectgolden
dc.subjectmineral acidsen
dc.subjectN-heterocyclic carbeneen
dc.subjectsulfateen
dc.titleGold- N -Heterocyclic Carbene Complexes of Mineral Acidsen
dc.typeArticleen
dc.identifier.journalChemCatChemen
dc.contributor.institutionEaStCHEM School of Chemistry; University of St Andrews; St Andrews KY16 9ST UKen
dc.contributor.institutionDepartment of Inorganic and Physical Chemistry; Ghent University; Krijgslaan 281-S3 9000 Gent Belgiumen
dc.contributor.institutionChemistry Department, College of Science; King Saud University; P.O. Box 2455 Riyadh 11451 Saudi Arabiaen
kaust.grant.numberOSR-2015-CCF-1974-03en
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