Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations

Handle URI:
http://hdl.handle.net/10754/623491
Title:
Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations
Authors:
Rueping, Magnus ( 0000-0003-4580-5227 ) ; Nikolaienko, Pavlo; Lebedev, Yury ( 0000-0003-2985-6876 ) ; Adams, Alina
Abstract:
A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in fluorination reactions.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Rueping M, Nikolaienko P, Lebedev Y, Adams A (2017) Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations. Green Chem. Available: http://dx.doi.org/10.1039/c7gc00877e.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Green Chem.
Issue Date:
4-May-2017
DOI:
10.1039/c7gc00877e
Type:
Article
ISSN:
1463-9262; 1463-9270
Sponsors:
We thank Dr Christoph Rauber for low temperature 19F-NMR spectra measurements. We would also like to thank Professor A. C. Filippou and Dr J. Tirree for the opportunity to record solid state IR spectra under an inert atmosphere.
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC00877E#!divAbstract
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorRueping, Magnusen
dc.contributor.authorNikolaienko, Pavloen
dc.contributor.authorLebedev, Yuryen
dc.contributor.authorAdams, Alinaen
dc.date.accessioned2017-05-14T12:03:58Z-
dc.date.available2017-05-14T12:03:58Z-
dc.date.issued2017-05-04en
dc.identifier.citationRueping M, Nikolaienko P, Lebedev Y, Adams A (2017) Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations. Green Chem. Available: http://dx.doi.org/10.1039/c7gc00877e.en
dc.identifier.issn1463-9262en
dc.identifier.issn1463-9270en
dc.identifier.doi10.1039/c7gc00877een
dc.identifier.urihttp://hdl.handle.net/10754/623491-
dc.description.abstractA protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in fluorination reactions.en
dc.description.sponsorshipWe thank Dr Christoph Rauber for low temperature 19F-NMR spectra measurements. We would also like to thank Professor A. C. Filippou and Dr J. Tirree for the opportunity to record solid state IR spectra under an inert atmosphere.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC00877E#!divAbstracten
dc.titleMetal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinationsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalGreen Chem.en
dc.contributor.institutionRWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, D-52074 Aachen, Germanyen
dc.contributor.institutionRWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 1, D-52074 Aachen, Germanyen
kaust.authorRueping, Magnusen
kaust.authorNikolaienko, Pavloen
kaust.authorLebedev, Yuryen
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