Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes

Handle URI:
http://hdl.handle.net/10754/623429
Title:
Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes
Authors:
Kalinina, Irina; Bekyarova, Elena; Sarkar, Santanu; Itkis, Mikhail E.; Niyogi, Sandip; Jha, Neetu; Wang, Qingxiao; Zhang, Xixiang ( 0000-0002-3478-6414 ) ; Al-Hadeethi, Yas Fadel; Haddon, Robert C.
Abstract:
This chapter employs purified pristine single-walled carbon nanotubes (SWNTs) and octadecylaminefunctionalized-SWNTs. These SWNTs are employed for investigate the potential of the SWNT sidewall to function as a hexahapto ligand for chromium (Cr), with in-depth characterization of the products using some of the techniques, such as thermogravimetric analysis (TGA), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS). Purified electric arc (EA)-produced SWNTs (P2-SWNT) and octadecylaminefunctionalized SWNTs were obtained from Carbon Solutions, Inc. The TEM images show the removal of the Cr particles from the outer surface of the SWNT bundles in the SWNT-Cr complexes after decomplexation; Cr attachment to the surface of the as-prepared complexes (η6-SWNT)Cr(CO)3 and (η6-SWNT-CONH(CH2)17CH3)Cr(CO)3 is clearly evident. The positions of the bands in the Raman spectra of SWNTs are sensitive to doping and thus the chapter examines the effect of complexation of the Cr(CO)3 and Cr(η6-benzene) units on the position of the G and 2D bands in the (η6-SWNT)Cr(CO)3 and (η6-SWNT)Cr(η6-benzene) complexes.
KAUST Department:
Advanced Nanofabrication and Thin Film Core Lab; Imaging and Characterization Core Lab
Citation:
Kalinina I, Bekyarova E, Sarkar S, Itkis ME, Niyogi S, et al. (2016) Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes. Chemical Synthesis and Applications of Graphene and Carbon Materials: 87–114. Available: http://dx.doi.org/10.1002/9783527648160.ch6.
Publisher:
Wiley-VCH Verlag GmbH & Co. KGaA
Journal:
Chemical Synthesis and Applications of Graphene and Carbon Materials
Issue Date:
17-Dec-2016
DOI:
10.1002/9783527648160.ch6
Type:
Book Chapter
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/9783527648160.ch6/summary
Appears in Collections:
Advanced Nanofabrication, Imaging and Characterization Core Lab; Book Chapters

Full metadata record

DC FieldValue Language
dc.contributor.authorKalinina, Irinaen
dc.contributor.authorBekyarova, Elenaen
dc.contributor.authorSarkar, Santanuen
dc.contributor.authorItkis, Mikhail E.en
dc.contributor.authorNiyogi, Sandipen
dc.contributor.authorJha, Neetuen
dc.contributor.authorWang, Qingxiaoen
dc.contributor.authorZhang, Xixiangen
dc.contributor.authorAl-Hadeethi, Yas Fadelen
dc.contributor.authorHaddon, Robert C.en
dc.date.accessioned2017-05-09T12:54:45Z-
dc.date.available2017-05-09T12:54:45Z-
dc.date.issued2016-12-17en
dc.identifier.citationKalinina I, Bekyarova E, Sarkar S, Itkis ME, Niyogi S, et al. (2016) Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes. Chemical Synthesis and Applications of Graphene and Carbon Materials: 87–114. Available: http://dx.doi.org/10.1002/9783527648160.ch6.en
dc.identifier.doi10.1002/9783527648160.ch6en
dc.identifier.urihttp://hdl.handle.net/10754/623429-
dc.description.abstractThis chapter employs purified pristine single-walled carbon nanotubes (SWNTs) and octadecylaminefunctionalized-SWNTs. These SWNTs are employed for investigate the potential of the SWNT sidewall to function as a hexahapto ligand for chromium (Cr), with in-depth characterization of the products using some of the techniques, such as thermogravimetric analysis (TGA), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS). Purified electric arc (EA)-produced SWNTs (P2-SWNT) and octadecylaminefunctionalized SWNTs were obtained from Carbon Solutions, Inc. The TEM images show the removal of the Cr particles from the outer surface of the SWNT bundles in the SWNT-Cr complexes after decomplexation; Cr attachment to the surface of the as-prepared complexes (η6-SWNT)Cr(CO)3 and (η6-SWNT-CONH(CH2)17CH3)Cr(CO)3 is clearly evident. The positions of the bands in the Raman spectra of SWNTs are sensitive to doping and thus the chapter examines the effect of complexation of the Cr(CO)3 and Cr(η6-benzene) units on the position of the G and 2D bands in the (η6-SWNT)Cr(CO)3 and (η6-SWNT)Cr(η6-benzene) complexes.en
dc.publisherWiley-VCH Verlag GmbH & Co. KGaAen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/9783527648160.ch6/summaryen
dc.subjectHexahapto-chromium complexesen
dc.subjectRaman spectroscopyen
dc.subjectSingle-walled carbon nanotubesen
dc.subjectThermogravimetric analysisen
dc.subjectTransmission electron microscopyen
dc.subjectX-ray photoelectron spectroscopyen
dc.titleSynthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubesen
dc.typeBook Chapteren
dc.contributor.departmentAdvanced Nanofabrication and Thin Film Core Laben
dc.contributor.departmentImaging and Characterization Core Laben
dc.identifier.journalChemical Synthesis and Applications of Graphene and Carbon Materialsen
dc.contributor.institutionUniversity of California - Riverside; Center for Nanoscale Science and Engineering; 104 Pierce Hall Annex Riverside CA 92521 USAen
dc.contributor.institutionUniversity of California - Riverside; Department of Chemistry; 104 Pierce Hall Annex Riverside CA 92521 USAen
dc.contributor.institutionKing Abdulaziz University; Department of Physics; Jeddah 21589 Kingdom of Saudi Arabiaen
dc.contributor.institutionUniversity of California - Riverside; Department of Chemical and Environmental Engineering; 104 Pierce Hall Annex Riverside CA 92521 USAen
kaust.authorWang, Qingxiaoen
kaust.authorZhang, Xixiangen
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