Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation

Handle URI:
http://hdl.handle.net/10754/623218
Title:
Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation
Authors:
Yue, Huifeng; Guo, Lin; Liao, Hsuan-Hung; Cai, Yunfei; Zhu, Chen; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
An efficient nickel-catalyzed decarbonylative amination reaction of aryl and heteroaryl esters has been achieved for the first time. The new amination protocol allows the direct interconversion of esters and amides into the corresponding amines and represents a good alternative to classical rearrangements as well as cross coupling reactions.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Yue H, Guo L, Liao H-H, Cai Y, Zhu C, et al. (2017) Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation. Angewandte Chemie International Edition 56: 4282–4285. Available: http://dx.doi.org/10.1002/anie.201611819.
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
15-Mar-2017
DOI:
10.1002/anie.201611819; 10.1002/ange.201611819
Type:
Article
ISSN:
1433-7851
Sponsors:
H.Y. and L.G. acknowledge the China Scholarship Council. H.-H.L. acknowledges the DAAD for a doctoral fellowship, Y.C. acknowledges the Alexander von Humboldt-Foundation for a fellowship. Support by King Abdullah University of Science and Technology (KAUST) is gratefully acknowledged.
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201611819/full
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorYue, Huifengen
dc.contributor.authorGuo, Linen
dc.contributor.authorLiao, Hsuan-Hungen
dc.contributor.authorCai, Yunfeien
dc.contributor.authorZhu, Chenen
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2017-04-13T11:51:01Z-
dc.date.available2017-04-13T11:51:01Z-
dc.date.issued2017-03-15en
dc.identifier.citationYue H, Guo L, Liao H-H, Cai Y, Zhu C, et al. (2017) Catalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activation. Angewandte Chemie International Edition 56: 4282–4285. Available: http://dx.doi.org/10.1002/anie.201611819.en
dc.identifier.issn1433-7851en
dc.identifier.doi10.1002/anie.201611819en
dc.identifier.doi10.1002/ange.201611819en
dc.identifier.urihttp://hdl.handle.net/10754/623218-
dc.description.abstractAn efficient nickel-catalyzed decarbonylative amination reaction of aryl and heteroaryl esters has been achieved for the first time. The new amination protocol allows the direct interconversion of esters and amides into the corresponding amines and represents a good alternative to classical rearrangements as well as cross coupling reactions.en
dc.description.sponsorshipH.Y. and L.G. acknowledge the China Scholarship Council. H.-H.L. acknowledges the DAAD for a doctoral fellowship, Y.C. acknowledges the Alexander von Humboldt-Foundation for a fellowship. Support by King Abdullah University of Science and Technology (KAUST) is gratefully acknowledged.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/anie.201611819/fullen
dc.subjectEstersen
dc.subjectNickelen
dc.subjectReaction Mechanismsen
dc.subjectAminationen
dc.subjectArenesen
dc.titleCatalytic Ester and Amide to Amine Interconversion: Nickel-Catalyzed Decarbonylative Amination of Esters and Amides by C−O and C−C Bond Activationen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAngewandte Chemie International Editionen
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen University; Landoltweg 1 52074 Aachen Germanyen
kaust.authorRueping, Magnusen
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