Polystyrene-supported cu(II)-R-Box as recyclable catalyst in asymmetric Friedel–Crafts reaction

Handle URI:
http://hdl.handle.net/10754/623184
Title:
Polystyrene-supported cu(II)-R-Box as recyclable catalyst in asymmetric Friedel–Crafts reaction
Authors:
Desyatkin, V. G.; Anokhin, M. V.; Rodionov, Valentin; Beletskaya, I. P.
Abstract:
The complex of copper(II) trifluoromethanesulfonate with chiral isopropyl bis(oxazoline) ligand (i-Pr-Box) was immobilized on accessible and inexpensive Merrifield resin according to a “click” procedure. The resulting catalyst showed high efficiency and recyclability in the asymmetric Friedel–Crafts alkylation of indole and its derivatives. The catalyst can be recycled five times without appreciable loss in activity and enantioselectivity.
KAUST Department:
King Abdullah University of Science and Technology, Thuwal, Saudi Arabia
Citation:
Desyatkin VG, Anokhin MV, Rodionov VO, Beletskaya IP (2016) Polystyrene-supported cu(II)-R-Box as recyclable catalyst in asymmetric Friedel–Crafts reaction. Russian Journal of Organic Chemistry 52: 1717–1727. Available: http://dx.doi.org/10.1134/S1070428016120010.
Publisher:
Pleiades Publishing Ltd
Journal:
Russian Journal of Organic Chemistry
Issue Date:
12-Feb-2017
DOI:
10.1134/S1070428016120010
Type:
Article
ISSN:
1070-4280; 1608-3393
Sponsors:
This study was performed under financial support by the Russian Science Foundation (project no. 14-23-00186).
Additional Links:
http://link.springer.com/article/10.1134/S1070428016120010
Appears in Collections:
Articles

Full metadata record

DC FieldValue Language
dc.contributor.authorDesyatkin, V. G.en
dc.contributor.authorAnokhin, M. V.en
dc.contributor.authorRodionov, Valentinen
dc.contributor.authorBeletskaya, I. P.en
dc.date.accessioned2017-04-13T11:50:59Z-
dc.date.available2017-04-13T11:50:59Z-
dc.date.issued2017-02-12en
dc.identifier.citationDesyatkin VG, Anokhin MV, Rodionov VO, Beletskaya IP (2016) Polystyrene-supported cu(II)-R-Box as recyclable catalyst in asymmetric Friedel–Crafts reaction. Russian Journal of Organic Chemistry 52: 1717–1727. Available: http://dx.doi.org/10.1134/S1070428016120010.en
dc.identifier.issn1070-4280en
dc.identifier.issn1608-3393en
dc.identifier.doi10.1134/S1070428016120010en
dc.identifier.urihttp://hdl.handle.net/10754/623184-
dc.description.abstractThe complex of copper(II) trifluoromethanesulfonate with chiral isopropyl bis(oxazoline) ligand (i-Pr-Box) was immobilized on accessible and inexpensive Merrifield resin according to a “click” procedure. The resulting catalyst showed high efficiency and recyclability in the asymmetric Friedel–Crafts alkylation of indole and its derivatives. The catalyst can be recycled five times without appreciable loss in activity and enantioselectivity.en
dc.description.sponsorshipThis study was performed under financial support by the Russian Science Foundation (project no. 14-23-00186).en
dc.publisherPleiades Publishing Ltden
dc.relation.urlhttp://link.springer.com/article/10.1134/S1070428016120010en
dc.titlePolystyrene-supported cu(II)-R-Box as recyclable catalyst in asymmetric Friedel–Crafts reactionen
dc.typeArticleen
dc.contributor.departmentKing Abdullah University of Science and Technology, Thuwal, Saudi Arabiaen
dc.identifier.journalRussian Journal of Organic Chemistryen
dc.contributor.institutionFaculty of Chemistry, Moscow State University, Moscow, Russiaen
dc.contributor.institutionFaculty of ChemistryMoscow State UniversityMoscowRussiaen
kaust.authorRodionov, Valentinen
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