Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

Handle URI:
http://hdl.handle.net/10754/623150
Title:
Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes
Authors:
Guo, Lin; Chatupheeraphat, Adisak; Rueping, Magnus ( 0000-0003-4580-5227 )
Abstract:
An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
Guo L, Chatupheeraphat A, Rueping M (2016) Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes. Angewandte Chemie International Edition 55: 11810–11813. Available: http://dx.doi.org/10.1002/anie.201604696.
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
25-Aug-2016
DOI:
10.1002/anie.201604696; 10.1002/ange.201604696
Type:
Article
ISSN:
1433-7851
Sponsors:
L. Guo was supported by the China Scholarship Council.
Additional Links:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201604696/abstract
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorGuo, Linen
dc.contributor.authorChatupheeraphat, Adisaken
dc.contributor.authorRueping, Magnusen
dc.date.accessioned2017-04-13T11:50:57Z-
dc.date.available2017-04-13T11:50:57Z-
dc.date.issued2016-08-25en
dc.identifier.citationGuo L, Chatupheeraphat A, Rueping M (2016) Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes. Angewandte Chemie International Edition 55: 11810–11813. Available: http://dx.doi.org/10.1002/anie.201604696.en
dc.identifier.issn1433-7851en
dc.identifier.doi10.1002/anie.201604696en
dc.identifier.doi10.1002/ange.201604696en
dc.identifier.urihttp://hdl.handle.net/10754/623150-
dc.description.abstractAn efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.en
dc.description.sponsorshipL. Guo was supported by the China Scholarship Council.en
dc.publisherWiley-Blackwellen
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/anie.201604696/abstracten
dc.subjectdecarbonylative cross-couplingsen
dc.subjectcopperen
dc.subjectestersen
dc.subjectnickelen
dc.subjectsilylationen
dc.titleDecarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanesen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalAngewandte Chemie International Editionen
dc.contributor.institutionInstitute of Organic Chemistry; RWTH Aachen University; Landoltweg 1 52074 Aachen Germanyen
kaust.authorRueping, Magnusen
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