Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

Handle URI:
http://hdl.handle.net/10754/623006
Title:
Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship
Authors:
Al Kordi, Mohamed; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Cairns, Amy; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Alkordi MH, Belmabkhout Y, Cairns A, Eddaoudi M (2017) Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship. IUCrJ 4: 131–135. Available: http://dx.doi.org/10.1107/S2052252516019060.
Publisher:
International Union of Crystallography (IUCr)
Journal:
IUCrJ
Issue Date:
9-Feb-2017
DOI:
10.1107/S2052252516019060
Type:
Article
ISSN:
2052-2525
Sponsors:
We acknowledge funding from King Abdullah University of Science and Technology (KAUST).
Is Supplemented By:
Alkordi, M. H., Belmabkhout, Y., Cairns, A., & Eddaoudi, M. (2017). CCDC 1528379: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1n9dkx; DOI:10.5517/ccdc.csd.cc1n9dkx; HANDLE:http://hdl.handle.net/10754/624599
Additional Links:
http://journals.iucr.org/m/issues/2017/02/00/lq5001/index.html
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorAl Kordi, Mohameden
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorCairns, Amyen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2017-03-15T07:15:27Z-
dc.date.available2017-03-15T07:15:27Z-
dc.date.issued2017-02-09en
dc.identifier.citationAlkordi MH, Belmabkhout Y, Cairns A, Eddaoudi M (2017) Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship. IUCrJ 4: 131–135. Available: http://dx.doi.org/10.1107/S2052252516019060.en
dc.identifier.issn2052-2525en
dc.identifier.doi10.1107/S2052252516019060en
dc.identifier.urihttp://hdl.handle.net/10754/623006-
dc.description.abstractThis study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.en
dc.description.sponsorshipWe acknowledge funding from King Abdullah University of Science and Technology (KAUST).en
dc.publisherInternational Union of Crystallography (IUCr)en
dc.relation.urlhttp://journals.iucr.org/m/issues/2017/02/00/lq5001/index.htmlen
dc.rightsThis is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.en
dc.rights.urihttp://creativecommons.org/licenses/by/2.0/uk/legalcodeen
dc.subjectdispersive interactionsen
dc.subjecthydrogen storageen
dc.subjectmetal-organic frameworksen
dc.subjectMOFsen
dc.subjecttailored pore geometryen
dc.titleMetal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationshipen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalIUCrJen
dc.eprint.versionPublisher's Version/PDFen
kaust.authorAl Kordi, Mohameden
kaust.authorBelmabkhout, Youssefen
kaust.authorCairns, Amyen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByAlkordi, M. H., Belmabkhout, Y., Cairns, A., & Eddaoudi, M. (2017). CCDC 1528379: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccdc.csd.cc1n9dkxen
dc.relation.isSupplementedByDOI:10.5517/ccdc.csd.cc1n9dkxen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624599en
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