Allyl borates: a novel class of polyhomologation initiators

Handle URI:
http://hdl.handle.net/10754/622785
Title:
Allyl borates: a novel class of polyhomologation initiators
Authors:
Wang, De ( 0000-0002-3737-6621 ) ; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Polymer Synthesis Laboratory
Citation:
Wang D, Hadjichristidis N (2017) Allyl borates: a novel class of polyhomologation initiators. Chem Commun 53: 1196–1199. Available: http://dx.doi.org/10.1039/c6cc09047h.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
24-Dec-2016
DOI:
10.1039/c6cc09047h
Type:
Article
ISSN:
1359-7345; 1364-548X
Sponsors:
The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C6CC09047H#!divAbstract
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorWang, Deen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2017-01-29T13:51:39Z-
dc.date.available2017-01-29T13:51:39Z-
dc.date.issued2016-12-24en
dc.identifier.citationWang D, Hadjichristidis N (2017) Allyl borates: a novel class of polyhomologation initiators. Chem Commun 53: 1196–1199. Available: http://dx.doi.org/10.1039/c6cc09047h.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.doi10.1039/c6cc09047hen
dc.identifier.urihttp://hdl.handle.net/10754/622785-
dc.description.abstractAllyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.en
dc.description.sponsorshipThe research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C6CC09047H#!divAbstracten
dc.titleAllyl borates: a novel class of polyhomologation initiatorsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentPolymer Synthesis Laboratoryen
dc.identifier.journalChem. Commun.en
kaust.authorWang, Deen
kaust.authorHadjichristidis, Nikolaosen
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