Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

Handle URI:
http://hdl.handle.net/10754/622725
Title:
Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity
Authors:
Yin, Dongdong; Li, Chuang; Ren, Hangxing; Shekhah, Osama ( 0000-0003-1861-9226 ) ; Liu, Jinxuan; Liang, Changhai
Abstract:
Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).
KAUST Department:
Advanced Membranes and Porous Materials Research Center
Citation:
Yin D, Li C, Ren H, Shekhah O, Liu J, et al. (2017) Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity. RSC Adv 7: 1626–1633. Available: http://dx.doi.org/10.1039/c6ra25722d.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
RSC Adv.
Issue Date:
5-Jan-2017
DOI:
10.1039/c6ra25722d
Type:
Article
ISSN:
2046-2069
Sponsors:
We gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (21673032, 21573031 and 21428301) and the Fundamental Research Funds for the Central Universities (DUT15ZD106 and DUT15RC(4)09).
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C6RA25722D#!divAbstract
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center

Full metadata record

DC FieldValue Language
dc.contributor.authorYin, Dongdongen
dc.contributor.authorLi, Chuangen
dc.contributor.authorRen, Hangxingen
dc.contributor.authorShekhah, Osamaen
dc.contributor.authorLiu, Jinxuanen
dc.contributor.authorLiang, Changhaien
dc.date.accessioned2017-01-25T08:57:40Z-
dc.date.available2017-01-25T08:57:40Z-
dc.date.issued2017-01-05en
dc.identifier.citationYin D, Li C, Ren H, Shekhah O, Liu J, et al. (2017) Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity. RSC Adv 7: 1626–1633. Available: http://dx.doi.org/10.1039/c6ra25722d.en
dc.identifier.issn2046-2069en
dc.identifier.doi10.1039/c6ra25722den
dc.identifier.urihttp://hdl.handle.net/10754/622725-
dc.description.abstractPd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).en
dc.description.sponsorshipWe gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (21673032, 21573031 and 21428301) and the Fundamental Research Funds for the Central Universities (DUT15ZD106 and DUT15RC(4)09).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C6RA25722D#!divAbstracten
dc.rightsThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/en
dc.titleEfficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivityen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.identifier.journalRSC Adv.en
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionLaboratory of Advanced Materials and Catalytic Engineering, Dalian University of Technology, Dalian, 116024, Chinaen
dc.contributor.institutionInstitute of Artificial Photosynthesis, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, Chinaen
kaust.authorShekhah, Osamaen
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