From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation

Handle URI:
http://hdl.handle.net/10754/622407
Title:
From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation
Authors:
Li, Baiyan; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Zhang, Yiming; Bhatt, Prashant; He, Hongming; Zhang, Daliang; Han, Yu ( 0000-0003-1462-1118 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Perman, Jason A.; Ma, Shengqian
Abstract:
We unveil a unique kinetic driven separation material for selectively removing linear paraffins from iso-paraffins via a molecular sieving mechanism. Subsequent carbonization and thermal treatment of CD-MOF-2, the cyclodextrin metal-organic framework, afforded a carbon molecular sieve with a uniform and reduced pore size of ca. 5.0 Å, and it exhibited highly selective kinetic separation of n-butane and n-pentane from iso-butane and iso-pentane, respectively. © The Royal Society of Chemistry.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division
Citation:
Li B, Belmabkhout Y, Zhang Y, Bhatt PM, He H, et al. (2016) From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation. Chem Commun 52: 13897–13900. Available: http://dx.doi.org/10.1039/C6CC08008A.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
4-Nov-2016
DOI:
10.1039/C6CC08008A
Type:
Article
ISSN:
1359-7345; 1364-548X
Sponsors:
The authors acknowledge the University of South Florida for financial support of this work. Y. B., P. M. B. and M. E. acknowledge the financial support of AMPM center collaborative funding CCF/1/1972-02-01 and CCF/1/1972-8-01. The authors thank Dr Zheng Niu, Kia Williams, and Dr Hui Yang for collecting the SEM images of CD-MOF-2.
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC08008A
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorLi, Baiyanen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorZhang, Yimingen
dc.contributor.authorBhatt, Prashanten
dc.contributor.authorHe, Hongmingen
dc.contributor.authorZhang, Daliangen
dc.contributor.authorHan, Yuen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorPerman, Jason A.en
dc.contributor.authorMa, Shengqianen
dc.date.accessioned2017-01-02T09:28:29Z-
dc.date.available2017-01-02T09:28:29Z-
dc.date.issued2016-11-04en
dc.identifier.citationLi B, Belmabkhout Y, Zhang Y, Bhatt PM, He H, et al. (2016) From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation. Chem Commun 52: 13897–13900. Available: http://dx.doi.org/10.1039/C6CC08008A.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.doi10.1039/C6CC08008Aen
dc.identifier.urihttp://hdl.handle.net/10754/622407-
dc.description.abstractWe unveil a unique kinetic driven separation material for selectively removing linear paraffins from iso-paraffins via a molecular sieving mechanism. Subsequent carbonization and thermal treatment of CD-MOF-2, the cyclodextrin metal-organic framework, afforded a carbon molecular sieve with a uniform and reduced pore size of ca. 5.0 Å, and it exhibited highly selective kinetic separation of n-butane and n-pentane from iso-butane and iso-pentane, respectively. © The Royal Society of Chemistry.en
dc.description.sponsorshipThe authors acknowledge the University of South Florida for financial support of this work. Y. B., P. M. B. and M. E. acknowledge the financial support of AMPM center collaborative funding CCF/1/1972-02-01 and CCF/1/1972-8-01. The authors thank Dr Zheng Niu, Kia Williams, and Dr Hui Yang for collecting the SEM images of CD-MOF-2.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC08008Aen
dc.titleFrom an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separationen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalChem. Commun.en
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL, United Statesen
kaust.authorBelmabkhout, Youssefen
kaust.authorBhatt, Prashanten
kaust.authorZhang, Daliangen
kaust.authorHan, Yuen
kaust.authorEddaoudi, Mohameden
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